Cited by 19Organic Electronics and PhotovoltaicsPolydiacetylene-based materials and applicationsPorphyrin and Phthalocyanine Chemistry

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Polydiacetylene-nested porphyrin as a potential light harvesting component in bulk heterojunction solar cells

Reanprayoon, Chawanwit, Gasiorowski, Jacek, Sukwattanasinitt, Mongkol, Sariciftci, Niyazi Serdar, Thamyongkit, Patchanita·2014·RSC Adv.

Abstract

A meso-substituted zinc-porphyrin embedded in a polydiacetylene web was prepared and tested for its potential in bulk heterojunction solar cells (BHJ-SCs). Light assisted formation of the polyenynes from diacetylenes coupled to the meso-position of the porphyrin were observed after UV-radiation, as evidenced by double and triple bond Raman-bands at 1446 and 2080 cm−1, respectively, and via UV absorption enhancement at 530–600 nm. Using cyclic voltammetry, Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energy levels were determined to be in an appropriate range for the photoactive materials in BHJ-SCs. Indeed, photoluminescence quenching indicated energy and/or charge transfer when the target material was used as a donor in combination with phenyl-C61-butyric acid methyl ester as acceptor in a blend. A photovoltaic effect of the BHJ-SCs was observed.

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Crossref · 10.1039/c3ra45373a

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  • BHJ OSCs based on the A22 donor showed poor device performances (PCE = 0.2%).

    “BHJ OSCs based on this donor showed poor device performances (PCE ¼ 0.2%).”
  • Thamyongkit and co-workers synthesized a polydiacetylene-nested porphyrin polymer A22.

    “In 2014, Thamyongkit and co-workers synthesized a polydiacetylene-nested porphyrin polymer ( A22 , Fig. 5). 37”
  • The Li group synthesized several porphyrin-containing polymers in which porphyrin was fused with quinoxaline and used as the electron-deficient unit to copolymerize with carbazole and oligothiophene pi-bridging groups (A23-A26).

    “Furthermore, the Li group employed a di ff erent concept to synthesize several porphyrin-containing polymers. Porphyrin was fused with quinoxaline and was used as the electron-de  cient unit to copolymerize with carbazole and oligothiophene p -bridging groups ( A23 -A26 , Fig. 5). 37”

Citations

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Metadata

Authors
Reanprayoon, C., Gasiorowski, J., Sukwattanasinitt, M., Sariciftci, N. S., & Thamyongkit, P.
Affiliations
  • Chulalongkorn University (TH)
  • Johannes Kepler University of Linz (AT)
Corresponding author
Thamyongkit, Patchanita
Venue
RSC Adv.
Published
2014
Volume
4
Issue
6
Pages
3045-3050
ISSN
2046-2069 (ISSN-L)
OpenAlex
W2020804552
Cited by
19
References
1
Citations by year
2025: 1 · 2022: 1 · 2021: 1 · 2020: 2 · 2019: 1 · 2018: 2 · 2017: 1 · 2016: 2 · 2015: 5 · 2014: 3
FWCI
2.00
Type
journal article
Language
en
Open access
closed
Locations
RSC Advances (publishedVersion)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
  • Physical Sciences › Chemistry › Organic Chemistry › Polydiacetylene-based materials and applications
  • Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
Keywords
polydiacetylene, zinc porphyrin, meso-substituted porphyrins, bulk heterojunction solar cells, light harvesting, UV-induced polymerization, HOMO-LUMO energy levels, photoluminescence quenching, charge transfer, energy transfer, organic solar cells

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