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Polydiacetylene-nested porphyrin as a potential light harvesting component in bulk heterojunction solar cells
Abstract
A meso-substituted zinc-porphyrin embedded in a polydiacetylene web was prepared and tested for its potential in bulk heterojunction solar cells (BHJ-SCs). Light assisted formation of the polyenynes from diacetylenes coupled to the meso-position of the porphyrin were observed after UV-radiation, as evidenced by double and triple bond Raman-bands at 1446 and 2080 cm−1, respectively, and via UV absorption enhancement at 530–600 nm. Using cyclic voltammetry, Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energy levels were determined to be in an appropriate range for the photoactive materials in BHJ-SCs. Indeed, photoluminescence quenching indicated energy and/or charge transfer when the target material was used as a donor in combination with phenyl-C61-butyric acid methyl ester as acceptor in a blend. A photovoltaic effect of the BHJ-SCs was observed.
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BHJ OSCs based on the A22 donor showed poor device performances (PCE = 0.2%).
“BHJ OSCs based on this donor showed poor device performances (PCE ¼ 0.2%).”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [37]
Thamyongkit and co-workers synthesized a polydiacetylene-nested porphyrin polymer A22.
“In 2014, Thamyongkit and co-workers synthesized a polydiacetylene-nested porphyrin polymer ( A22 , Fig. 5). 37”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [37]
The Li group synthesized several porphyrin-containing polymers in which porphyrin was fused with quinoxaline and used as the electron-deficient unit to copolymerize with carbazole and oligothiophene pi-bridging groups (A23-A26).
“Furthermore, the Li group employed a di ff erent concept to synthesize several porphyrin-containing polymers. Porphyrin was fused with quinoxaline and was used as the electron-de cient unit to copolymerize with carbazole and oligothiophene p -bridging groups ( A23 -A26 , Fig. 5). 37”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [37]
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Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311
Metadata
- Authors
- Reanprayoon, C., Gasiorowski, J., Sukwattanasinitt, M., Sariciftci, N. S., & Thamyongkit, P.
- Affiliations
- Chulalongkorn University (TH)
- Johannes Kepler University of Linz (AT)
- Corresponding author
- Thamyongkit, Patchanita
- Venue
- RSC Adv.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 4
- Issue
- 6
- Pages
- 3045-3050
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2020804552
- Cited by
- 19
- References
- 1
- Citations by year
- 2025: 1 · 2022: 1 · 2021: 1 · 2020: 2 · 2019: 1 · 2018: 2 · 2017: 1 · 2016: 2 · 2015: 5 · 2014: 3
- FWCI
- 2.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- RSC Advances (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Chemistry › Organic Chemistry › Polydiacetylene-based materials and applications
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Keywords
- polydiacetylene, zinc porphyrin, meso-substituted porphyrins, bulk heterojunction solar cells, light harvesting, UV-induced polymerization, HOMO-LUMO energy levels, photoluminescence quenching, charge transfer, energy transfer, organic solar cells
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