The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
A Cu(i) metal–organic framework with 4-fold helical channels for sensing anions
Abstract
A new Cu(I) metal–organic framework, {[Cu(pytpy)]·NO3·CH3OH}∞ (1), which is a 4-fold interpenetrating 3D framework with (10,3)-b topology, has been synthesized by self-assembly of Cu(NO3)2·3H2O with 2,4,6-tris(4-pyridyl)pyridine (pytpy) in mixed-solvent. The guest methanol molecules in the channels of 1 could be replaced by water molecules via a single-crystal-to-single-crystal (SC–SC) process, and the hydrated complex could serve as a host for sensing anions with different geometries which can be conveniently recognized visually. Moreover, the desolvated complex shows selective uptake of CO2 over N2 at ambient temperature.
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Cited by
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Self-citationA Water‐Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants
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Ionic metal-organic frameworks (iMOFs): Design principles and applications
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Recent Progress in Stimulus-Responsive Two-Dimensional Metal–Organic Frameworks
Li, C., Wang, K., Li, J., & Zhang, Q. (2020) · ACS Materials Letters · doi:10.1021/acsmaterialslett.0c00148 · Cited by 252
Metadata
- Authors
- Chen, Y.-Q., Li, G.-R., Chang, Z., Qu, Y.-K., Zhang, Y.-H., & Bu, X.-H.
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 4
- Issue
- 9
- Pages
- 3678
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2108564398
- Cited by
- 262
- References
- 22
- FWCI
- 21.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, Y.-Q., Li, G.-R., Chang, Z., Qu, Y.-K., Zhang, Y.-H., & Bu, X.-H. (2013). A Cu(i) metal–organic framework with 4-fold helical channels for sensing anions. Chemical Science. https://doi.org/10.1039/c3sc00057e
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