The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Fluoride Ion Sensing by an Anion−π Interaction
Abstract
We report the discovery of a supramolecular interaction (anion-π and charge/electron transfer, CT/ET) involving fluoride ion and π-electron deficient colorless naphthalene diimide (NDI) receptors. Strong electronic interactions between lone-pair electrons of F(-) ion and π*-orbitals of the NDI unit lead to an unprecedented F(-)→NDI ET event, which produces an orange colored NDI(•-) radical anion. Further reduction of NDI(•-) by another F(-) ion produces a pink colored NDI(2-) dianion, rendering NDI a colorimetric F(-) sensor. Preorganization of two NDI units in overlapping positions using folded linkers improves their selectivity and sensitivity for the F(-) ion significantly, allowing F(-) detection at nM concentration in 85:15 DMSO/H(2)O solutions.
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Cites
Fluoride in Drinking Water: A Review on the Status and Stress Effects
Ayoob, S., & Gupta, A. K. (2006) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380600678112 · Cited by 1,355
Schottel, B. L., Chifotides, H. T., & Dunbar, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b614208g · Cited by 1,133
Fluoride Ion Complexation and Sensing Using Organoboron Compounds
Wade, C. R., Broomsgrove, A. E. J., Aldridge, S., & Gabbaï, F. P. (2010) · Chemical Reviews · doi:10.1021/cr900401a · Cited by 1,089
Anion receptor chemistry: highlights from 2007
Caltagirone, C., & Gale, P. A. (2009) · Chem. Soc. Rev. · doi:10.1039/b806422a · Cited by 859
Anion–π Interactions: Do They Exist?
Quiñonero, D., Garau, C., Rotger, C., Frontera, A., Ballester, P., Costa, A., & Deyà, P. M. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020916)41:18<3389::aid-anie3389>3.0.co;2-s · Cited by 756
Recognition and sensing of fluoride anion
Cametti, M., & Rissanen, K. (2009) · Chemical Communications · doi:10.1039/b902069a · Cited by 654
Synthetic molecules that fold into a pleated secondary structure in solution
Lokey, R. S., & Iverson, B. L. (1995) · Nature · doi:10.1038/375303a0 · Cited by 548
Interaction of Anions with Perfluoro Aromatic Compounds
Alkorta, I., Rozas, I., & Elguero, J. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025693t · Cited by 527
Experimental evidence for the functional relevance of anion–π interactions
Dawson, R. E., Hennig, A., Weimann, D. P., Emery, D., Ravikumar, V., Montenegro, J., Takeuchi, T., Gabutti, S., Mayor, M., Mareda, J., et al. (2010) · Nature Chemistry · doi:10.1038/nchem.657 · Cited by 477
Anhydrous Tetrabutylammonium Fluoride
Sun, H., & DiMagno, S. G. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0440497 · Cited by 381
Cited by
Applications of Supramolecular Anion Recognition
Busschaert, N., Caltagirone, C., Van Rossom, W., & Gale, P. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00099 · Cited by 1,249
Chudzinski, M. G., McClary, C. A., & Taylor, M. S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202096f · Cited by 293
Li, C., Chueh, C., Ding, F., Yip, H., Liang, P., Li, X., & Jen, A. K. ‐. (2013) · Advanced Materials · doi:10.1002/adma.201300580 · Cited by 278
Liu, L., Liu, Q., Li, R., Wang, M.-S., & Guo, G.-C. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c10183 · Cited by 141
Metadata
- Authors
- Guha, S., & Saha, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-29
- Volume
- 132
- Issue
- 50
- Pages
- 17674-17677
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2002138370
- Cited by
- 507
- References
- 22
- FWCI
- 12.71
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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