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Carbene-stabilized main group radicals and radical ions
Open accessAbstract
Shortly after their discovery at the end of the 80s, stable singlet carbenes have been recognized as excellent ligands for transition metal based catalysts, and as organo-catalysts in their own right. At the end of the 2000s, it has been shown that they can coordinate main group elements in their zero oxidation state, and even activate small molecules. This review covers examples in the literature dealing with the most recent application of stable singlet carbenes, namely their use to stabilize radicals and radical ions that are otherwise unstable.
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Citations
Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
Melaimi, M., Jazzar, R., Soleilhavoup, M., & Bertrand, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702148 · Cited by 788
Self-citationN-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field
Wang, Y., & Robinson, G. H. (2014) · Inorganic Chemistry · doi:10.1021/ic502231m · Cited by 266
Metadata
- Authors
- Martin, C. D., Soleilhavoup, M., & Bertrand, G.
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 4
- Issue
- 8
- Pages
- 3020
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W1971080513
- Cited by
- 499
- References
- 1
- FWCI
- 23.10
- Type
- journal article
- Language
- en
- Open access
- green
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- Martin, C. D., Soleilhavoup, M., & Bertrand, G. (2013). Carbene-stabilized main group radicals and radical ions. Chemical Science. https://doi.org/10.1039/c3sc51174j
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