The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases
Abstract
In industry, cryogenic rectification for separating xenon from other noble gases such as krypton and argon is an energy and capital intensive process. Here we show that a microporous metal–organic framework, namely Co3(HCOO)6 is capable of effective capture and separation of xenon from other noble gases. Henry's constant, isosteric heat of adsorption (Qst), and IAST selectivity are calculated based on single component sorption isotherms. Having the highest Qst reported to date, Co3(HCOO)6 demonstrates high adsorption capacity for xenon and its IAST selectivity for Xe–Kr is the largest among all MOFs investigated to date. To mimic real world conditions, breakthrough experiments are conducted on Xe–Kr binary mixtures at room temperature and 1 atmosphere. The results are consistent with the calculated data. These findings show that Co3(HCOO)6 is a promising candidate for xenon capture and purification. Our gas adsorption measurements and molecular simulation study also reveal that the adsorption of xenon represents the first example of commensurate adsorption of atomic gases near ambient conditions.
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Citations
Cites
Industrial Gas Handbook: Gas Separation and Purification
Kerry, F. G. (2007) · doi:10.1201/9781420008265 · Cited by 297
Cited by
Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks
Wang, H., Lustig, W. P., & Li, J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00885f · Cited by 695
Self-citationSeparation of rare gases and chiral molecules by selective binding in porous organic cages
Chen, L., Reiss, P. S., Chong, S. Y., Holden, D., Jelfs, K. E., Hasell, T., Little, M. A., Kewley, A., Briggs, M. E., Stephenson, A., et al. (2014) · Nature Materials · doi:10.1038/nmat4035 · Cited by 666
Metal–organic framework with optimally selective xenon adsorption and separation
Banerjee, D., Simon, C. M., Plonka, A. M., Motkuri, R. K., Liu, J., Chen, X., Smit, B., Parise, J. B., Haranczyk, M., & Thallapally, P. K. (2016) · Nature Communications · doi:10.1038/ncomms11831 · Cited by 466
Potential of Metal–Organic Frameworks for Separation of Xenon and Krypton
Banerjee, D., Cairns, A. J., Liu, J., Motkuri, R. K., Nune, S. K., Fernandez, C. A., Krishna, R., Strachan, D. M., & Thallapally, P. K. (2015) · Accounts of Chemical Research · doi:10.1021/ar5003126 · Cited by 428
What Are the Best Materials To Separate a Xenon/Krypton Mixture?
Simon, C. M., Mercado, R., Schnell, S. K., Smit, B., & Haranczyk, M. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01475 · Cited by 275
Metadata
- Authors
- Wang, H., Yao, K., Zhang, Z., Jagiello, J., Gong, Q., Han, Y., & Li, J.
- Venue
- Chem. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 5
- Issue
- 2
- Pages
- 620-624
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2158545001
- Cited by
- 238
- References
- 1
- FWCI
- 10.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, H., Yao, K., Zhang, Z., Jagiello, J., Gong, Q., Han, Y., & Li, J. (2014). The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases. Chem. Sci. https://doi.org/10.1039/c3sc52348a
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