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Cited by 361

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A novel zwitterionic polyelectrolyte grafted PVDF membrane for thoroughly separating oil from water with ultrahigh efficiency

Zhu, Yuzhang, Zhang, Feng, Wang, Dong, Pei, Xian Feng, Zhang, Wenbin, Jin, Jian·2013·Journal of Materials Chemistry A

Abstract

Oil–water separation is a worldwide challenge because of increasingly oily wastewater, as well as frequent oil spill accidents. We report in this work the fabrication of a zwitterionic polyelectrolyte brush (poly(3-(N-2-methacryloxyethyl-N,N-dimethyl) ammonatopropanesultone), abbreviated as PMAPS)-grafted poly(vinylidene fluoride) (PMAPS-g-PVDF) membrane via a surface-initiated atom transfer radical polymerization (SI-ATRP) technique for separating oil from water. By tuning polymerization time, a superhydrophilic and underwater superoleophobic PMAPS-g-PVDF membrane was successfully prepared. The membrane can be applied for thoroughly separating dispersed oil from water with ultrahigh separation efficiency >99.999% in terms of rejection coefficient. The oil contents after one-time separation of a selection of oil–water mixtures are all less than 10 ppm and some of them are even lower than 2 ppm. These values are much lower than the standard minimum requirements of the international regulations for wastewater discharging. The oil-adhesion force between an oil droplet and the membrane surface was measured to be less than 1 μN. Due to the ultralow oil adhesion, the membrane exhibits an excellent antifouling property to oil and is easily recyclable.

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Metadata

Authors
Zhu, Y., Zhang, F., Wang, D., Pei, X. F., Zhang, W., & Jin, J.
Venue
Journal of Materials Chemistry A
Published
2013
Volume
1
Issue
18
Pages
5758
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W2066345449
Cited by
361
References
1
FWCI
10.26
Type
journal article
Language
en
Open access
closed

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Zhu, Y., Zhang, F., Wang, D., Pei, X. F., Zhang, W., & Jin, J. (2013). A novel zwitterionic polyelectrolyte grafted PVDF membrane for thoroughly separating oil from water with ultrahigh efficiency. Journal of Materials Chemistry A. https://doi.org/10.1039/c3ta01598j

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.