The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction
Abstract
Catalysts for oxygen reduction reaction (ORR) are crucial in fuel cells. Developing metal-free catalyst with high activity at low-cost and high-volume production remains a great challenge. Here, we report a novel type of nitrogen-doped nanoporous carbon nanosheets derived from a conveniently available and accessible plant, Typha orientalis. The nanosheets have high surface area (the highest surface area can be 898 m2 g−1), abundant micropores and high content of nitrogen (highest content of 9.1 at.%). The typical product exhibits an unexpected, surprisingly high ORR activity. In alkaline media, it exhibits similar catalytic activity but superior tolerance to methanol as compared to commercial 20% Pt/C. In acidic media as well, it shows excellent catalytic ability, stability and tolerance to methanol. This low-cost, simple and readily scalable approach provides a straightforward route to synthesize excellent electrocatalysts directly from biomass, which may find broad applications in the fields of supercapacitors, sensors, and gas uptake.
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Citations
Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
Wu, G., More, K. L., Johnston, C. M., & Zelenay, P. (2011) · Science · doi:10.1126/science.1200832 · Cited by 3,984
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
Engineering carbon materials from the hydrothermal carbonization process of biomass
Hu, B., Wang, K., Wu, L., Yu, S., Antonietti, M., & Titirici, M. (2010) · Advanced Materials · doi:10.1002/adma.200902812 · Cited by 1,765
Self-citationHigh oxygen-reduction activity and durability of nitrogen-doped graphene
Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219
Cited by
Fu, Y., Yu, H., Jiang, C., Zhang, T., Zhan, R., Li, X., Li, J., Tian, J., & Yang, R. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201705094 · Cited by 523
Efficient Metal‐Free Electrocatalysts from N‐Doped Carbon Nanomaterials: Mono‐Doping and Co‐Doping
Gao, K., Wang, B., Tao, L., Cunning, B. V., Zhang, Z., Wang, S., Ruoff, R. S., & Qu, L. (2019) · Advanced Materials · doi:10.1002/adma.201805121 · Cited by 486
Xie, Y., Chen, X., Sun, K., Zhang, J., Lai, W., Liu, H., & Wang, G. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202301833 · Cited by 197
Self-citationZhou, H., Zhang, J., Amiinu, I. S., Zhang, C., Liu, X., Tu, W., Pan, M., & Mu, S. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp00174b · Cited by 128
Du, L., Zhang, G., Liu, X., Hassanpour, A., Dubois, M., Tavares, A. C., & Sun, S. (2020) · Carbon Energy · doi:10.1002/cey2.73 · Cited by 120
Metadata
- Authors
- Chen, P., Wang, L.-K., Wang, G., Gao, M.-R., Ge, J., Yuan, W.-J., Shen, Y.-H., Xie, A.-J., & Yu, S.-H.
- Venue
- Energy Environ. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-10-09
- Volume
- 7
- Issue
- 12
- Pages
- 4095-4103
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2133487805
- Cited by
- 576
- References
- 5
- FWCI
- 22.70
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, P., Wang, L.-K., Wang, G., Gao, M.-R., Ge, J., Yuan, W.-J., Shen, Y.-H., Xie, A.-J., & Yu, S.-H. (2014). Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction. Energy Environ. Sci. https://doi.org/10.1039/c4ee02531h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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