The fluorescence properties and aggregation behavior of tetraphenylethene–perylenebisimide dyads
Abstract
Perylene-bisimides (PBIs) modified with tetraphenylethene (TPE) at N-terms show unique X-aggregation and are non-fluorescent in solution, aggregate and solid film due to the photoinduced charge transfer between TPE and PBI subunits.
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Molecules possessing predominant X-type stacking are still quite rare, mainly due to the difficulty of molecular design and structural modification requirements.
“While cross-dipole stacking has been addressed as a preferred motif for aggregated state emission, molecules possessing predominant X-type stacking are still quite rare. This is mainly due to the difficulty of the molecular design and structural modification requirements.93−96”
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- Authors
- Wang, Y. J., Li, Z., Tong, J., Shen, X. Y., Qin, A., Sun, J. Z., & Tang, B. Z.
- Affiliations
- MoE Key Laboratory of Macromolecule Synthesis and Functionalization
- Zhejiang University (CN)
- State Key Laboratory of Luminescent Materials and Devices (CN)
- Hong Kong University of Science and Technology (HK)
- Corresponding author
- Sun, Jing Zhi
- Tang, Ben Zhong
- Venue
- Journal of Materials Chemistry C
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 3
- Issue
- 15
- Pages
- 3559-3568
- ISSN
- 2050-7526 (ISSN-L)
- 2050-7534
- OpenAlex
- W2057882857
- Cited by
- 74
- References
- 59
- Citations by year
- 2026: 1 · 2025: 5 · 2024: 4 · 2023: 5 · 2022: 9 · 2021: 5 · 2020: 4 · 2019: 7 · 2018: 11 · 2017: 9 · 2016: 10 · 2015: 3
- FWCI
- 4.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry C (publishedVersion)
- Rare & Special e-Zone (The Hong Kong University of Science and Technology) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Keywords
- tetraphenylethylene, perylene diimide, dyads, aggregation-induced emission, fluorescence, photoinduced charge transfer, solid-state aggregation
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