Direct observation of the dealloying process of a platinum–yttrium nanoparticle fuel cell cathode and its oxygenated species during the oxygen reduction reaction
Abstract
Size-selected 9 nm Pt x Y nanoparticles have recently shown an outstanding catalytic activity for the oxygen reduction reaction, representing a promising cathode catalyst for proton exchange membrane fuel cells (PEMFCs).
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The leakage level (or Pt enrichment) and the thickness of the dealloyed region vary with different alloys, preparation techniques and electrochemical treatments.
“The leakage level (or Pt enrichment) and the thickness of the dealloyed region vary with different alloys, preparation techniques and electrochemical treatments.18,19”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [19]
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- Authors
- Malacrida, P., Sanchez Casalongue, H. G., Masini, F., Kaya, S., Hernández-Fernández, P., Deiana, D., Ogasawara, H., Stephens, I. E. L., Nilsson, A., & Chorkendorff, I.
- Affiliations
- Technical University of Denmark (DK)
- Joint Center for Artificial Photosynthesis (JCAP), Energy Innovation Hub, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS 976-JCAP, Berkeley, California 94720, USA
- Koç University (TR)
- Center for Individual Nanoparticle Functionality (CINF), Department of Physics, Technical University of Denmark (DTU), DK-2800 Lyngby, Denmark
- SLAC National Accelerator Laboratory (US)
- Lawrence Berkeley National Laboratory (US)
- Corresponding author
- Chorkendorff, Ib
- ORCID
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 17
- Issue
- 42
- Pages
- 28121-28128
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W1997661046
- Cited by
- 62
- References
- 55
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 6 · 2023: 8 · 2022: 5 · 2021: 3 · 2020: 6 · 2019: 8 · 2018: 6 · 2017: 7 · 2016: 9
- FWCI
- 2.17
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Physical Chemistry Chemical Physics (publishedVersion)
- PubMed (publishedVersion)
- Digital Collections portal (Koç University) (submittedVersion)
- Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- electrochemical dealloying, oxygen reduction reaction, acid leaching, size-selected nanoparticles, catalyst stability, membrane degradation
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