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Synthesis of two-dimensional titanium nitride Ti4N3(MXene)
Abstract
We report on the synthesis of the first two-dimensional transition metal nitride, Ti4N3-based MXene. In contrast to the previously reported MXene synthesis methods - in which selective etching of a MAX phase precursor occurred in aqueous acidic solutions - here a molten fluoride salt is used to etch Al from a Ti4AlN3 powder precursor at 550 °C under an argon atmosphere. We further delaminated the resulting MXene to produce few-layered nanosheets and monolayers of Ti4N3Tx, where T is a surface termination (F, O, or OH). Density functional theory calculations of bare, non-terminated Ti4N3 and terminated Ti4N3Tx were performed to determine the most energetically stable form of this MXene. Bare and functionalized Ti4N3 are predicted to be metallic. Bare Ti4N3 is expected to show magnetism, which is significantly reduced in the presence of functional groups.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
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Electric Field Effect in Atomically Thin Carbon Films
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Two-dimensional atomic crystals
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Anisotropic Etching of SiC Whiskers
Cambaz, G. Z., Yushin, G. N., Gogotsi, Y., & Lutsenko, V. G. (2006) · Nano Letters · doi:10.1021/nl051858v · Cited by 103
Self-citation
Cited by
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Self-citationTransition metal nitrides for electrochemical energy applications
Wang, H., Li, J., Li, K., Lin, Y., Chen, J., Gao, L., Nicolosi, V., Xiao, X., & Lee, J.-M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00415d · Cited by 983
Jiang, X., Kuklin, A. V., Baev, A., Ge, Y., Ågren, H., Zhang, H., & Prasad, P. N. (2020) · Physics Reports · doi:10.1016/j.physrep.2019.12.006 · Cited by 914
A Review on MXene Synthesis, Stability, and Photocatalytic Applications
Murali, G., Reddy Modigunta, J. K., Park, Y. H., Lee, J.-H., Rawal, J., Lee, S.-Y., In, I., & Park, S.-J. (2022) · ACS Nano · doi:10.1021/acsnano.2c04750 · Cited by 668
Recent advance in MXenes: A promising 2D material for catalysis, sensor and chemical adsorption
Zhu, J., Ha, E., Zhao, G., Zhou, Y., Huang, D., Yue, G., Hu, L., Sun, N., Wang, Y., Lee, L. Y. S., et al. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.012 · Cited by 659
Metadata
- Authors
- Urbankowski, P., Anasori, B., Makaryan, T., Er, D., Kota, S., Walsh, P. L., Zhao, M., Shenoy, V. B., Barsoum, M. W., & Gogotsi, Y.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 8
- Issue
- 22
- Pages
- 11385-11391
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2404226482
- Cited by
- 1,371
- References
- 4
- FWCI
- 21.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Urbankowski, P., Anasori, B., Makaryan, T., Er, D., Kota, S., Walsh, P. L., Zhao, M., Shenoy, V. B., Barsoum, M. W., & Gogotsi, Y. (2016). Synthesis of two-dimensional titanium nitride Ti4N3(MXene). Nanoscale. https://doi.org/10.1039/c6nr02253g
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