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Click chemistry synthesis, stereocomplex formation, and enhanced thermal properties of well-defined poly( l -lactic acid)- b -poly( d -lactic acid) stereo diblock copolymers
Abstract
PLLA- b -PDLAs with well-controlled molecular weights, compositions, highly enhanced stereocomplexation ability, and thermal resistance were synthesized by ROP and click chemistry.
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“Till now, the only successful way of copolymerizing with PLA macroinitiator has been achieved by either using specific additives or modifying the metal complex by bulky ligands, which then act as initiator and therefore present a serious limitation for the generation of triblock copolymers [23].”
From A simple and general approach for the synthesis of biodegradable triblock copolymers by organocatalytic ROP from poly(lactide) macroinitiators (2020) · cites this paper as [23]
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Poly(lactic acid) stereocomplexes based molecular architectures: Synthesis and crystallization
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Metadata
- Authors
- Han, L., Xie, Q., Bao, J., Shan, G., Bao, Y., & Pan, P.
- Affiliations
- State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 8
- Issue
- 6
- Pages
- 1006-1016
- ISSN
- 1759-9954
- 1759-9962
- Cited by
- 64
- References
- 56
- Language
- en
- Funders
- National Natural Science Foundation of China (21422406)
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