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Porphyrin dimers as donors for solution-processed bulk heterojunction organic solar cells
Abstract
We synthesize a novel class of porphyrin dimers consisting of two zinc-metalated porphyrin units covalently linked through ethynyl or butadiyne group as electron donors for the fabrication of organic bulk heterojunction (BHJ) solar cells.
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Dimers usually show a higher efficiency in comparison with monomers.
“Dimers usually show a higher e ffi ciency in comparison with monomers.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [113]
The higher intrinsic carrier mobility of F10 is due to the longer π-conjugation bridge.
“The higher intrinsic carrier mobility of F10 is due to the longer p -conjugation bridge.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [113]
Intrinsic hole mobilities of F9 and F10 are 4.5×10−4 and 6.3×10−4 cm2 V−1 s−1, respectively.
“Intrinsic hole mobilities of F9 and F10 are 4.5 -10 4 and 6.3 -10 4 cm 2 V 1 s 1 , respectively.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [113]
F10 blend processed from a mixed solvent of 3% v/v 1-chloronaphathalene (CN) in o-DCB improved efficiency to 2.03%.
“Its e ffi ciency can be further improved to 2.03% when the F10 blend was processed from a mixed solvent of 3% v/v 1-chloronaphathalene (CN) in o -DCB.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [113]
F9 and F10 with PC71BM showed PCEs of 1.24% and 1.73%, respectively.
“The two donors fabricated with PC71BM showed PCEs of 1.24% ( F9 ) and 1.73% ( F10 ).”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [113]
Citations
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New soluble porphyrin bearing a pyridinylethynyl group as donor for bulk heterojunction solar cells
Sharma, G. D., Daphnomili, D., Biswas, S., & Coutsolelos, A. G. (2013) · Organic Electronics · doi:10.1016/j.orgel.2013.03.023 · Cited by 30
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Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311
Metadata
- Authors
- Hsu, F.-C., Hsieh, M.-K., Kashi, C., Yeh, C.-Y., Lin, T.-Y., & Chen, Y.-F.
- Affiliations
- National United University (TW)
- National Taiwan Ocean University (TW)
- National Chung Hsing University (TW)
- National Taiwan University (TW)
- Corresponding author
- Hsu, Fang-Chi
- Yeh, Chen-Yu
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 6
- Issue
- 65
- Pages
- 60626-60632
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2432314468
- Cited by
- 11
- References
- 6
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 2 · 2022: 1 · 2021: 1 · 2020: 1 · 2018: 2 · 2017: 2
- FWCI
- 0.62
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- RSC Advances (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Cancer Research › Photodynamic Therapy Research Studies
- Keywords
- porphyrin dimers, zinc porphyrin, electron donors, bulk heterojunction solar cells, organic solar cells, solution processing, ethynyl linker
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