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Abuse tolerance behavior of layered oxide-based Li-ion battery during overcharge and over-discharge
Abstract
The main reason for the degradation of slightly overcharged NCM/graphite full cells was found to be the unstable crystal structure of the NCM material at a relatively high delithiation state.
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Overcharging causes cathode overdelithiation and anode over-lithiation; cathode suffers irreversible structural change when overdelithiated, followed by dissolution of transition metal ions and active material decomposition.
“When a cell is overcharged, the cathode is overdelithiated (no active lithium available) and the anode is over-lithiated (no more 'room' for lithium).The cathode material suffers from irreversible structural change when overdelithiated [33], followed by the dissolution of transition metal ions (such as Mn 2+ ) and active material decomposition [34].”
From Data-driven health estimation and lifetime prediction of lithium-ion batteries: A review (2019) · cites this paper as [33]
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Metadata
- Authors
- Qian, K., Li, Y., He, Y.-B., Liu, D., Zheng, Y., Luo, D., Li, B., & Kang, F.
- Affiliations
- Tsinghua Shenzhen International Graduate School (CN)
- University of Science and Technology Beijing (CN)
- Corresponding author
- Li, Baohua
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 6
- Issue
- 80
- Pages
- 76897-76904
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2502186300
- Cited by
- 106
- References
- 33
- Citations by year
- 2026: 7 · 2025: 9 · 2024: 10 · 2023: 17 · 2022: 14 · 2021: 14 · 2020: 11 · 2019: 13 · 2018: 8 · 2017: 3
- FWCI
- 3.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- RSC Advances (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- abuse tolerance, lithium-ion batteries, layered oxide cathodes, NCM cathode, graphite anode, overcharging, battery degradation
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