Cited by 52Advanced Photocatalysis TechniquesIron oxide chemistry and applicationsTiO2 Photocatalysis and Solar Cells

A modular device for large area integrated photoelectrochemical water-splitting as a versatile tool to evaluate photoabsorbers and catalysts

Becker, J.-P., Turan, B., Smirnov, V., Welter, K., Urbain, F., Wolff, J., Haas, S., Finger, F.·2017·Journal of Materials Chemistry A

Abstract

We present a stand-alone integrated solar water-splitting device with an active area of 64 cm 2 and a long-term stable operation. The modular setup of the device provides a versatile tool to integrate and evaluate various combinations of photoelectrodes and catalysts.

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Crossref · 10.1039/c6ta10688a

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  • The integrated water-splitting module at zero bias maintained its current value under constant operation for 80 min.

    “In addition, the operation curves are plotted in Figure 9r, corresponding to the point of operation of the module at zero bias (V = 0), maintaining its current value under constant operation for 80 min.”
  • During water-splitting, the evolution of H2 and O2 gas volumes over time was collected, as expected, for a faradaic efficiency of 100% via Faraday's law of electrolysis.

    “During water-splitting, the evolution of H 2 and O 2 gas volumes over time was collected, as expected, for a faradaic efficiency of 100% via Faraday's law of electrolysis (Figure 9s).”
  • The 64-unit solar cell module exhibited homogeneous characteristics, with efficiency between 9.8% and 10.3%.

    “The 64-unit solar cell module exhibited homogeneous characteristics, with efficiency between 9.8% and 10.3% (Figure 9p).”
  • Becker et al. presented a stand-alone integrated solar water-splitting module with an active area of 64 cm2, demonstrating long-term stable operation.

    “Becker et al. [251] presented a stand-alone integrated solar water-splitting module with an active area of 64 cm 2 , demonstrating long-term stable operation (Figure 9n).”
  • Different active areas of triple junction solar cells (1 × 1, 2 × 2, 3 × 3, 7.3 × 7.3 cm2) show a decrease in the fill factor from 71.2% to 56.1%.

    “Different active areas of triple junction solar cells (1 × 1, 2 × 2, 3 × 3, 7.3 × 7.3 cm 2 ) were compared to exhibit a trade-off between electrical and optical properties (conductivity and transmittance), showing a decrease in the fill factor from 71.2% to 56.1%.”

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Authors
Becker, J.-P., Turan, B., Smirnov, V., Welter, K., Urbain, F., Wolff, J., Haas, S., & Finger, F.
Affiliations
Forschungszentrum Jülich (DE)
Corresponding author
Becker, J.-P.
Venue
Journal of Materials Chemistry A
Published
2017
Volume
5
Issue
10
Pages
4818-4826
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W2577178734
Cited by
52
References
0
Citations by year
2026: 2 · 2025: 2 · 2024: 7 · 2023: 6 · 2022: 5 · 2021: 4 · 2020: 9 · 2019: 7 · 2018: 6 · 2017: 4
FWCI
1.91
Type
journal article
Language
en
Open access
closed
Locations
  • Journal of Materials Chemistry A (publishedVersion)
  • JuSER (Forschungszentrum Jülich) (submittedVersion)
Funders
  • Bundesministerium für Bildung und Forschung (03X3581B)
  • Deutsche Forschungsgemeinschaft (Priority Program 1613)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Iron oxide chemistry and applications
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
Keywords
photoelectrochemical water splitting, solar water splitting, photoabsorbers, photoelectrodes, catalysts, modular device, device stability, catalyst evaluation

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