Cited by 30Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Substituent effects in magnesium tetraethynylporphyrin with two diketopyrrolopyrrole units for bulk heterojunction organic solar cells

Ogumi, Keisuke, Nakagawa, Takafumi, Okada, Hiroshi, Sakai, Ryohei, Wang, Huan, Matsuo, Yutaka·2017·Journal of Materials Chemistry A

Abstract

Acceptor–donor–acceptor conjugated magnesium porphyrins showed a power conversion efficiency of 5.73%, high open-circuit voltage of 0.79 V, or an extended incident photon-to-current conversion efficiency spectrum to 1100 nm, depending on the substituents.

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Crossref · 10.1039/c7ta07576f

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1 of 1 references verified0 citation errors · 0 not checkable

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  • D11 showed the best efficiency of 5.73% among D10-D13 due to the phase-separated structure resulting from the n-hexyl substituent on the aryl groups.

    “D11 showed the best e ffi ciency of 5.73% among these molecules due to the phase-separated structure resulting from the n -hexyl substituent on the aryl groups.”
  • All D10-D13 molecules showed strong absorption at around 500 nm (Soret band) and around 800 nm (Q-band).

    “All molecules showed strong absorption at around 500 nm (Soret band) and around 800 nm (Q-band).”

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Authors
Ogumi, K., Nakagawa, T., Okada, H., Sakai, R., Wang, H., & Matsuo, Y.
Affiliations
  • Tokyo Metropolitan Industrial Technology Research Institute (JP)
  • The University of Tokyo (JP)
  • Fujipream Corporation (Japan) (JP)
  • University of Science and Technology of China (CN)
Corresponding author
Matsuo, Yutaka
Venue
Journal of Materials Chemistry A
Published
2017
Volume
5
Issue
44
Pages
23067-23077
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W2764339863
Cited by
30
References
1
Citations by year
2025: 3 · 2024: 2 · 2023: 3 · 2022: 3 · 2021: 1 · 2020: 4 · 2019: 8 · 2018: 6
FWCI
2.05
Type
journal article
Language
en
Open access
closed
Locations
Journal of Materials Chemistry A (publishedVersion)
Funders
  • University of Science and Technology of China
  • JSPS (JP15H05760, JP16H04187, JP17K04970, JP17K19116)
  • MEXT
  • Strategic Promotion of Innovative Research and Development
  • JST
  • NEDO
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
  • Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
  • Health Sciences › Medicine › Pulmonary and Respiratory Medicine › Photodynamic Therapy Research Studies
Keywords
magnesium porphyrin, diketopyrrolopyrrole, substituent effects, bulk heterojunction, organic solar cells, power conversion efficiency, open-circuit voltage, external quantum efficiency

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