Nickel phosphide polymorphs with an active (001) surface as excellent catalysts for water splitting
Open accessAbstract
We report the temperature-controlled synthesis of two nickel phosphide polymorphs, Ni 2 P and Ni 5 P 4 , by phosphorization of Ni foil or foams using phosphine gas, and their excellent catalytic activity toward hydrogen evolution reaction.
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Nickel phosphides as HER electrocatalysts improve their catalytic activity in the order Ni5P4>Ni2P>Ni12P5 with increasing P/Ni ratio.
“Furthermore, nickel phosphides as the HER electrocatalysts improve their catalytic activity in the order Ni5P4>Ni2P>Ni12P5 with the increase of the ratio of P/Ni [38,39].”
From Ultrathin nickel phosphide nanosheet aerogel electrocatalysts derived from Ni-alginate for hydrogen evolution reaction (2020) · cites this paper as [38]
Cites
Liu, P., & Rodriguez, J. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0540019 · Cited by 1,240 · see citing works
Pan, Y., Liu, Y., Zhao, J., Yang, K., Liang, J., Liu, D., Hu, W., Liu, D., Liu, Y., & Liu, C. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04867a · Cited by 652 · see citing works
Wang, X., Kolen'ko, Y. V., Bao, X., Kovnir, K., & Liu, L. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502577 · Cited by 554 · see citing works
Kucernak, A. R. J., & Naranammalpuram Sundaram, V. N. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta03468f · Cited by 379 · see citing works
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Lai, S., Lv, C., Chen, S., Lu, P., She, X., Wan, L., Wang, H., Sun, J., Yang, D., & Zhao, X. (2020) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2019.152727 · Cited by 22 · see citing works
- Authors
- Jung, C. S., Park, K., Lee, Y., Kwak, I. H., Kwon, I. S., Kim, J., Seo, J., Ahn, J.-P., & Park, J.
- Affiliations
- Korea University (KR)
- Korean Association Of Science and Technology Studies (KR)
- Corresponding author
- Park, Jeunghee
- Venue
- CrystEngComm
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 21
- Issue
- 7
- Pages
- 1143-1149
- ISSN
- 1466-8033 (ISSN-L)
- OpenAlex
- W2912729642
- Cited by
- 23
- References
- 4
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 3 · 2023: 5 · 2022: 2 · 2021: 2 · 2020: 4 · 2019: 4
- FWCI
- 0.64
- Type
- journal article
- Language
- en
- Open access
- Locations
- CrystEngComm (publishedVersion)
- Civil War Book Review (submittedVersion)
- Funders
- Korea University
- Korea Basic Science Institute (D39700)
- Ministry of Science and Technology
- Pohang University of Science and Technology
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Iron oxide chemistry and applications
- Keywords
- nickel phosphide, polymorphs, Ni5P4, (001) surface, water splitting, hydrogen evolution reaction, electrocatalysis, phosphorization, phosphine, nickel foam, temperature-controlled synthesis
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