A sustainable biochar catalyst synergized with copper heteroatoms and CO 2 for singlet oxygenation and electron transfer routes

Dynamic Molecular Structure of Plant Biomass-Derived Black Carbon (Biochar)

Keiluweit, M., Nico, P. S., Johnson, M. G., & Kleber, M. (2010) · Environmental Science & Technology · doi:10.1021/es9031419 · Cited by 3,230

Cobalt-catalyzed sulfate radical-based advanced oxidation: A review on heterogeneous catalysts and applications

Hu, P., & Long, M. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.07.024 · Cited by 2,189

Development of biochar-based functional materials: toward a sustainable platform carbon material

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Mechanism of Base Activation of Persulfate

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Metal-Free Carbocatalysis in Advanced Oxidation Reactions

Duan, X., Sun, H., & Wang, S. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00535 · Cited by 1,329

Defect engineering in photocatalytic materials

Bai, S., Zhang, N., Gao, C., & Xiong, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.08.058 · Cited by 1,245

Persulfate Activation on Crystallographic Manganese Oxides: Mechanism of Singlet Oxygen Evolution for Nonradical Selective Degradation of Aqueous Contaminants

Zhu, S., Li, X., Kang, J., Duan, X., & Wang, S. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b04669 · Cited by 1,245

Catalytic Removal of Aqueous Contaminants on N-Doped Graphitic Biochars: Inherent Roles of Adsorption and Nonradical Mechanisms

Zhu, S., Huang, X., Ma, F., Wang, L., Duan, X., & Wang, S. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b01817 · Cited by 1,179

Identifying the Nonradical Mechanism in the Peroxymonosulfate Activation Process: Singlet Oxygenation Versus Mediated Electron Transfer

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Biosorption and me

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Comparative study of peroxymonosulfate activation with H2O2 activation by Cu–N doped biochar derived from peach gum network for rapid antibiotic removal

Tan, Z., Sheng, Y., Yang, S. S., Jin, T., Shi, Z., Yang, J., & Wang, D. (2025) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2025.03.025 · Cited by 11

N-doped citrate-sludge-derived carbon (NCSC) effectively promotes peroxymonosulfate activation for perfluorooctanoic acid (PFOA) removal with surface-mediated electron transfer mechanism

Fu, S., Zhang, Y., Xu, X., Tan, Y., & Zhu, L. (2023) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2023.115592 · Cited by 10

Glycerol Valorization Towards Glycolic Acid Production Over Cu‐Based Biochar Catalyst

Liao, S., Tian, Q., Xiao, Y., Qin, D., Li, J., & Hu, C. (2022) · ChemSusChem · doi:10.1002/cssc.202201537 · Cited by 10

Hydrogen peroxide activation by in-situ-loaded CuS/biochar photocatalyst: The critical role of sulfur species in regulating active species

Ying, D., Fang, Y., Niu, H., Du, N., Chen, M., Yan, R., Huang, Y., Tan, Y., & Wang, S. (2024) · Separation and Purification Technology · doi:10.1016/j.seppur.2024.129004 · Cited by 9

Degradation of tetracycline by Fe/V@C activated peroxymonosulfate: Synergistic interactions of active substances in a multiphase catalytic process

Lin, Y., Huang, T., Zhu, H., Xu, Q., Zhang, Y., Wang, M., & Shen, S. (2024) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2024.106441 · Cited by 10

Enhanced electron transfer for superior Cr(VI) removal in water using ball-milled aluminum/biochar composite with embedded structure: Efficiency and mechanism

Zhang, S., Li, L., Zhao, Z., Li, Y., Shen, L., & Zhang, S. (2025) · Separation and Purification Technology · doi:10.1016/j.seppur.2025.131809 · Cited by 10

Cu Nanoparticles Supported on Fe3O4@SiO2@N-Doped Carbon Core–Shell Nanocomposites for C–N Coupling Reactions in Water

Ge, X. Q., Zhang, H., Ge, M., Liu, X., & Yuan, S. (2021) · ACS Applied Nano Materials · doi:10.1021/acsanm.1c02248 · Cited by 9

Synergistic effects of Vis/H2O2/LaFe1−xCuxO3 and Vis/PDS/LaFe1−xCuxO3 for quinoline degradation: Performance and mechanism

Zhang, L., Fan, L., Fan, J., Li, Y., Sun, P., Han, J., & Zhanchun, F. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.108322 · Cited by 9

Coal-derived char for improving mechanical performance and microstructural characteristics of concrete

Dipta, I. A., Ng, K. W., Lau, C., & Yu, H. W. (2025) · Journal of Sustainable Cement-Based Materials · doi:10.1080/21650373.2025.2465979 · Cited by 8

Mechanistic insights into nitrogen doping effects on cobalt-loaded biochar for peroxymonosulfate Catalysis

Wang, C., Xie, Y., Li, N., Tian, H., Qu, J., Cai, Y., Chen, G., & Tan, Q. (2026) · Bioresource Technology · doi:10.1016/j.biortech.2026.134179 · Cited by 8

Ultrafast removal of sulfamethoxazole across a wide pH range via EDTA-functionalized Cu-modified tobacco straw biochar: Efficient adsorption and targeted degradation

Wang, H., Zhang, Q., Wang, Z., Fu, B., Xue, G., Ji, H., Ding, Y., & Wu, Y. (2025) · Separation and Purification Technology · doi:10.1016/j.seppur.2025.134439 · Cited by 7

Green synthesis of Co–Ag biochar catalysts from rice husk using hydrothermal carbonization concentrate for efficient NaBH₄ hydrolysis

Velez, M., Murillo, H. A., Debut, A., Ducos, P., Niebieskikwiat, D., Torres, F. J., & Ponce, S. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.120410 · Cited by 8

Catalytic performance of activated lignite chars on biomass tar cracking

Li, C., Zhang, H., Gong, X., & Zhang, Y. (2023) · Environmental Science and Pollution Research · doi:10.1007/s11356-023-26541-0 · Cited by 7

Defect-driven bifunctional Cu/N co-doped biochar for synchronized adsorption and instant catalysis in organic pollutant degradation

Yu, R., He, F., Wang, J., Jia, Z., Liu, C., & Zhou, H. (2025) · Journal of Environmental Management · doi:10.1016/j.jenvman.2025.127703 · Cited by 6

Machine learning-enabled optimization of biochar resource utilization and carbon mitigation pathways: mechanisms and challenges

Jiang, Y., Shiyu, X. I. E., Abou‐Elwafa, S. F., Mukherjee, S., Singh, R. K., Tran, H.-T., Shi, J., Trindade, H., Zhang, T., & Chen, Q. (2025) · Biochar X · doi:10.48130/bchax-0025-0003 · Cited by 9

New insights into the electron-transfer mechanism of Cr(VI) activation by carbon materials for simultaneously enhanced Cr(VI) detoxicate and acetaminophen oxidation: the role of defect structures

Zhao, Y., Yang, B., Liang, Z., Ji, H., & Li, Z. (2025) · Water Research · doi:10.1016/j.watres.2025.125301 · Cited by 5

Efficient degradation of tetracycline by PMS activation using N, P-doped hollow carbon spheres with spatial confinement effect

Chen, L., Hu, J., He, Y., JunCang, W., Hong, Y., & Chen, W. (2026) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2026.109585 · Cited by 5

Are We Truly Accurately Quantifying HO • Using Benzoic Acid Hydroxylation in Engineered HO • -Producing Systems?

Zheng, W., Li, Q., Fu, H., Luo, X., Li, H., Duan, W., Liu, C., Chen, T. H., Dang, Z., & Feng, C. (2026) · Environmental Science & Technology · doi:10.1021/acs.est.6c00461 · Cited by 5

Waste derived biochar for water purification: the roles of redox properties

Sun, H., Chen, T., Ji, L., Tian, D., Li, X., & Sun, C. (2024) · Waste Disposal & Sustainable Energy · doi:10.1007/s42768-024-00211-4 · Cited by 5

Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

Zhang, H., Qi, X., Wang, Z., Jin, L., & Shen, Y. (2024) · New Journal of Chemistry · doi:10.1039/d4nj00509k · Cited by 5

Comparative Investigation of Biochar-Based Nanocomposites Over Pristine Biochar: An Overview

Mishra, D., Jain, S., Khare, P., & Singh, R. (2023) · Advances in Science, Technology & Innovation/Advances in science, technology & innovation · doi:10.1007/978-3-031-28873-9_5 · Cited by 4

Enhanced peroxymonosulfate activation by oxalic acid-activated lignin-derived carbon to degrade sulfamethoxazole: performance and mechanism

Huang, W., Llopart-Roca, P., Nieto-Sandoval, J., Bayarri, B., & Sans, C. (2025) · Green Chemical Engineering · doi:10.1016/j.gce.2025.09.001 · Cited by 3

Effective abatement of tetracycline in water by activation of peracetic acid by the copper oxide loaded on straw-derived biochar via the enhanced copper redox cycling

Wan, Y., Yan, Z., Pan, H., Zhao, X., & Fang, Z. (2025) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2025.109367 · Cited by 3

Biochar-reinforced biodegradable mulching films: Toward climate-resilient and sustainable agriculture

Amusat, S. O., Dube, S., Mnyango, J. I., Hlangothi, S. P., Fouda-Mbanga, B. G., Seyisi, T., Mhlanga, S. D., & Tywabi-Ngeva, Z. (2026) · Bioresource Technology Reports · doi:10.1016/j.biteb.2025.102525 · Cited by 5

An alkali-modified biochar-supported single-atom catalyst with enhanced mass transfer for efficient nitrate electrolysis

Yang, X., Liu, D., Zhang, Y., Fu, C., Qiu, Z., Li, Y., Zhuang, Z., & Yu, B. (2026) · Nano Research · doi:10.26599/nr.2026.94908413 · Cited by 3

Achievement of biochar photocatalytic performance by synergistic oxidation of sulfuric acid/hydrogen peroxide: Towards revealing the mechanism of synergistic oxidation on photocatalytic performance

Jiang, X., Liu, J., Wang, F., Zhang, D., & Yi, W. (2024) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2024.106292 · Cited by 3

Preparation of Slow-Release Potassium Persulfate Microcapsules and Application in Degradation of PAH-Contaminated Soil

Wu, H., Yang, Y., Sun, L., Wang, Y., Wang, H., & Wang, X. (2024) · Water · doi:10.3390/w16213045 · Cited by 2

Screening of typical pollutants in groundwater polluted by nitrogen heterocyclic pesticides and removal mechanism of iron-doped biochar

Fu, R., Liu, K., Qu, D., Qi, Y., Qi, X., Weng, C., Hao, Y., Na, L., & Wen, C. (2025) · Journal of Environmental Sciences · doi:10.1016/j.jes.2025.11.016 · Cited by 2

Uniformly dispersed CoS on N-doped carbon framework for selective peroxymonosulfate activation via high-valent cobalt-oxo species

Liu, Y., Zhang, X., Wang, Z., Liu, M., Chen, X., & Wang, J. (2026) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2026.121771 · Cited by 2

Biochar-assisted advanced oxidation processes for wastewater treatment

Dhaka, R. K., Jain, K., Pittman, C. U. J., Mlsna, T., Mohan, D., Singh, K. P., Rani, P., Dhaka, S., & Trakal, L. (2022) · Elsevier eBooks · doi:10.1016/b978-0-12-822225-6.00023-3 · Cited by 2

Biochar Catalyst for Oxidation Reactions

Kumar, R. (2024) · Sustainable materials and technology · doi:10.1007/978-981-97-6544-7_9 · Cited by 1

Biochar-Based Catalysts for the Production of Chemical and Energy

Garg, U., & Azim, Y. (2024) · Sustainable materials and technology · doi:10.1007/978-981-97-4252-3_8 · Cited by 2

Efficient hydrogen conversion of toluene via biochar-supported Fe-Cu bimetallic catalyst under CO2-steam synergistic conditions

Zhang, J., Wang, X., Jin, H. Z., Wang, J., Yang, H., Dong, C., Li, G., Tang, Y., Liu, H., & Ye, C. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.116401 · Cited by 1

Engineering biochar with Cu N active sites for promoted ofloxacin removal via radical and nonradical peroxymonosulfate activation

Manickavasagam, G., Hamidon, T. S., Hussin, M. H., Saaid, M., & Oh, W. (2025) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2025.108429 · Cited by 1

Vivianite@interstitial-carbon doped MoS2-induced peroxymonosulfate activation for norfloxacin removal: Performance, mechanism and regeneration

He, F., Wang, J., Fang, J., Yu, R., Jia, Z., & Zhou, H. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.119124 · Cited by 1

Cu2O-modified magnetic iron-nitrogen co-doped biochar effective peroxymonosulfate activation for degradation of phthalate esters in reclaimed water

Wu, J., Wang, Y., Bai, J., Li, X., Gao, Y., Li, G., Zheng, Y., Huo, M., & Wang, X. (2026) · Environmental Research · doi:10.1016/j.envres.2026.124635 · Cited by 1

Graphite Carbon Supported Single-Atom Iron Catalyst Activates Persulfate for Phenol Degradation: Radical and Non-Radical Synergistic Mechanism

Li, S., Chu, M., Tian, Y., Yang, J., Yao, S., & Xiao, M. (2025) · Water Air & Soil Pollution · doi:10.1007/s11270-025-08938-4 · Cited by 1

Biochar-augmented carbon-negative concrete

Huang, G., Shi, Y., Zhou, Y., Li, H., Ye, P., Guo, B., Yan, J. H., & Wang, L. (2026) · Elsevier eBooks · doi:10.1016/b978-0-443-22037-1.00006-9 · Cited by 1

Calcination atmosphere tuning of HZSM-5 supported metal catalysts for improved selectivity in toluene catalytic cracking to H2 and simulation optimization

Niu, Z., Hu, Q., Lou, H., Zhang, J., Wang, X., Jin, H., Bu, Z., Li, G., Tang, Y., & Ye, C. (2026) · Fuel · doi:10.1016/j.fuel.2026.139889 · Cited by 1

Enhancement of CO 2 Conversion With Biochar in Dielectric Barrier Discharge

Mei, D., Cai, Y., Wang, Y., Sun, M., Liu, S., & Fang, Z. (2026) · Plasma Processes and Polymers · doi:10.1002/ppap.70209 · Cited by 1

Nitrogen-doped FeCu bimetal porous composite derived from solid wastes for activating peroxymonosulfate for efficient degradation emerging contaminants

Zheng, K., Yang, C., Huang, J. Y., Pan, C., Lu, Y., Li, W., & Qin, C. (2026) · Chemical Engineering Journal · doi:10.1016/j.cej.2026.179273 · Cited by 1

Activation of peroxymonosulfate by catalysts derived from water treatment plant sludge for the simultaneous removal of Disperse Blue 56 and phosphates

Tang, X., Jin, H., Zou, J., Liu, S., Li, F., & Zhou, Z. (2022) · Environmental Science and Pollution Research · doi:10.1007/s11356-022-24792-x · Cited by 1

Biobased materials in sustainable development of catalysis

Murthy, H. C. A., Bhattacharya, T., Kelele, K. G., Gebretsadik, A., & Abayneh, A. (2023) · Elsevier eBooks · doi:10.1016/b978-0-323-91677-6.00017-9 · Cited by 1

Unlocking the solution-phase molecular transformation of biochar during intensive rainfall events: Implications for the long-term carbon cycle under climate change

Sun, Y., Xu, Z., He, M., Alessi, D. S., & Tsang, D. C. W. (2024) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2024.176708 · Cited by 2

LED illumination-assisted activation of peroxydisulfate by heterogeneous Cu2S under alkaline condition for efficient organic pollutants removal

Luo, C.-W., Jiang, L., Xie, C., Huang, D.-G., & Jiang, T.-J. (2024) · Environmental Research · doi:10.1016/j.envres.2024.120634 · Cited by 1

Enhanced Degradation of Phenol by Catalytic Wet Oxidation Over Novel Ceria Promoted Mesoporous Silica Supported Ru-Fe3o4 Catalyst: A Combined Experimental and Dft StudyPreprint

Roy, S., & Mondal, D. K. (2022) · SSRN Electronic Journal · doi:10.2139/ssrn.4005778 · Cited by 1

Peroxide‐Based Biochar‐Assisted Advanced Oxidation

Cao, Y., Zhang, Q., Sun, Y., & Tsang, D. W. (2023) · Wiley eBooks · doi:10.1002/9781119764403.ch12 · Cited by 1

Biochar and Catalysis: An Approach from Patent Analysis

Barragán-Ocaña, A., Olmos-Peña, S., Santos-Rubio, L. R., & Cardona, E.-Y. H. (2024) · ACS symposium series · doi:10.1021/bk-2024-1479.ch003

Upcycling of iron-enriched sludge into valued iron-carbon composite catalyst for efficient Fenton-like reaction

Liu, C., Yao, Y., Zhao, W., Chen, Z., Zhao, X., Gao, J., Yang, X., Xiao, C., Qi, J., Zhou, Y., et al. (2025) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2025.116736

Beyond pure precursors: Towards oxygen reduction reaction activity enhancement in PEM fuel cells from recycled mining waste

Orozco, D. C., Ossa-Gallego, R., Orozco-Silva, C., Muñoz-Montes, V., Boudjelida, S., Pagot, G., Negro, E., Noto, V. D., & Calderón-Gutiérrez, J. (2025) · Electrochimica Acta · doi:10.1016/j.electacta.2025.147979

Synergistic effect of endogenous mineral components and N configurations on the enhanced removal of bisphenol a by Enteromorpha prolifera-derived biochar: batch adsorption, DFT calculation, and mechanistic insight

Wu, W., Li, R., Han, Z., Tian, R., Feng, D., Li, S., & Bai, B. (2026) · Separation and Purification Technology · doi:10.1016/j.seppur.2026.137392

Valorisation énergétique de la biomasse par gazéification : conversion du goudron par des biochars issus de résidu de biomasse en lit fixe

Benhalilou, M. R. (2022) · theses.fr (ABES) · doi:10.70675/b497937bz083fz4d74z8ff3zddc3e18a5dd3

Biochar-Driven Persulfate Activation in Advanced Oxidation Processes: A Bibliometric Retrospective and Perspective on Emerging Trends

Zhang, C. Z., Wang, C., Lyu, C., Zhong, S., Li, C., Shen, M., Wang, S., & Jing, L. (2026) · Water Air & Soil Pollution · doi:10.1007/s11270-026-09545-7

Comparative study on sustainable degradation of sulfamethoxazole via peroxymonosulfate activation by different transition metal-doped biochars

Wang, C., Tian, H., Tian, J., Chu, C., Chen, K., Wu, X., Ye, Z., Qu, J., Cai, Y., & Tan, Q. (2026) · Environmental Functional Materials · doi:10.1016/j.efmat.2026.04.004

MoS2-activated peroxymonosulfate (PMS) and peroxydisulfate (PDS) for low-level urea removal from reclaimed water toward ultrapure water production

Wang, Q., Cui, X., Zhao, W., Zhang, M., & Zhang, X. (2026) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2026.123841

Synergistic activation of persulfate by oxychar and LDH for efficient degradation of PLA microplastics

Ji, C., Wang, S., Meng, Q., Wang, H. J., Zhao, X., Wang, H. J., Liu, A., 张春芳, Qin, Z., Han, B., et al. (2026) · Advanced Industrial and Engineering Polymer Research · doi:10.1016/j.aiepr.2026.07.002

Electro-enhanced nonradical peroxydisulfate activation over graphitic carbon-supported single-atom iron for ciprofloxacin mineralization

Li, S., Wang, Z., Tian, Y., Chu, M., Yao, S., Xiao, M., & Yang, J. (2026) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2026.124505

Catalytic Degradation of Glyphosate via Cu-Doped Peanut-Shell Biochar: A High-Performance Heterogeneous System

Ortiz-Marin, A. D., Renzini, M. S., & Saux, C. (2026) · International Journal of Environmental Research · doi:10.1007/s41742-026-01215-0

Bamboo-derived Co/Mn co-modified biochar for peroxymonosulfate activation: Rapid sulfamethoxazole degradation and toxicity assessment

Lin, H., Cheng, Z., Zou, W., Chen, D., Chen, J., & Zhang, H. (2026) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2026.142122

Immobilization of heavy metals in polluted soil systems using biochar-based materials

Kumpatla, R., Nayak, A., Reddy, B. M., Choudhary, R., Tomar, M., Yadav, S., Kumar, K. S. N. P., Meghana, T. H. V., & Nandipamu, T. M. K. (2026) · Elsevier eBooks · doi:10.1016/b978-0-443-27656-9.00016-9

Sustainable remediation with an electroactive biochar system: mechanisms and perspectives

Wan, Z., Sun, Y., Tsang, D. C. W., Hou, D., Cao, X., Zhang, S., Gao, B., & Ok, Y. S. (2020) · Green Chemistry · doi:10.1039/d0gc00717j · Cited by 162

Iron-based biochar as efficient persulfate activation catalyst for emerging pollutants removal: A review

Lu, J., Lu, Q., Di, L., Zhou, Y., & Zhou, Y. (2023) · Chinese Chemical Letters · doi:10.1016/j.cclet.2023.108357 · Cited by 116

Insights into biochar supported atomically dispersed cobalt as an efficient peroxymonosulfate activator for sulfamethoxazole degradation: robust performance, ROS and surface electron-transfer pathways

Gu, C., Zhang, Y., He, P., Zhu, J., & Gan, M. (2022) · Environmental Science Nano · doi:10.1039/d2en00490a · Cited by 16

A novel way of activating peroxysulfate by zero-valent copper and ferroferric oxide co-modified biochar to remove bisphenol A in aqueous solution: Performance, mechanism and potential toxicity

Chen, K., Zhou, L., Xu, W., Hu, Z., Jia, M., & Liu, L. (2022) · Applied Catalysis A General · doi:10.1016/j.apcata.2022.118575 · Cited by 33

Chrome shaving-derived biochar as efficient persulfate activator: Ti-induced charge distribution modulation for 1O2 dominated nonradical process

Guo, L., Zhao, L., Tang, Y., Zhou, J., & Shi, B. Q. (2022) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2022.160838 · Cited by 16