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A highly active alkane dehydrogenation catalyst: stabilization of dihydrido rhodium and iridium complexes by a P–C–P pincer ligand
Abstract
The novel P–C–P pincer complex, [IrH2{C6H3(CH22PBut2)2}] has long-term stability and 200 ° C and catalyses the transfer dehydrogenation of cyclooctnane to cyclooctene at the rate of 12 turnovers min1 min–1.
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Citations
Cited by
Bond Activation and Catalysis by Ruthenium Pincer Complexes
Gunanathan, C., & Milstein, D. (2014) · Chemical Reviews · doi:10.1021/cr5002782 · Cited by 958
Jia, X., Qin, C., Friedberger, T., Guan, Z., & Huang, Z. (2016) · Science Advances · doi:10.1126/sciadv.1501591 · Cited by 534
“A dual catalyst system containing a supported “pincer”-ligated iridium complex, (PCP)Ir (1) (24, 25) (Fig.”
BackgroundEngle, K. M., & Yu, J.-Q. (2013) · The Journal of Organic Chemistry · doi:10.1021/jo400159y · Cited by 531
Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes
Kumar, A., Bhatti, T. M., & Goldman, A. S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00247 · Cited by 346
C−H Functionalization of Commodity Polymers
Williamson, J. B., Lewis, S. E., Johnson, R. R., Manning, I. M., & Leibfarth, F. A. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201810970 · Cited by 313
Metadata
- Authors
- Gupta, M., Hagen, C., Flesher, R. J., Kaska, W. C., & Jensen, C. M.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1996
- Issue
- 17
- Pages
- 2083-2084
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2069708019
- Cited by
- 329
- References
- 0
- FWCI
- 5.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A highly active alkane dehydrogenation catalyst: stabilization of dihydrido rhodium and iridium complexes by a P–C–P pincer ligand. https://app.cochat.ai/papers/10.1039/cc9960002083
- The paper
- Gupta, M., Hagen, C., Flesher, R. J., Kaska, W. C., & Jensen, C. M. (1996). A highly active alkane dehydrogenation catalyst: stabilization of dihydrido rhodium and iridium complexes by a P–C–P pincer ligand. Chem. Commun. https://doi.org/10.1039/cc9960002083
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
