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A series of Rb 4 Ln 2 (P 2 S 6 )(PS 4 ) 2 (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P V S 4 ] 3− and [P IV 2 S 6 ] 4−
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A new series of rare earth thiophosphates, Rb 4 Ln 2 (P 2 S 6 )(PS 4 ) 2 (Ln = La, Ce, Pr, Nd, Sm, Gd), containing two unique thiophosphate motifs, [P V S 4 ] 3− and [P IV 2 S 6 ] 4− , were synthesized using the high temperature molten flux crystal growth method by RbBr flux.
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In Ac4P8S28Tl8, the similarity to the structure of La2P4S14Rb4 is not immediately apparent from the unit cells, but Ac compounds are expected to be isomorphous with their La analogues, and Tl1+ and Rb1+ are close in size and identical in charge states, making the similarity evident.
“In the case of Ac4P8S28Tl8, the similarity to the structure of La2P4S14Rb424 is not immediately apparent from the unit cells. However, we would expect Ac compounds would be isomorphous with their La analogues. Tl1+ and Rb1+ are also close in size and identical in their charge states. The similarity of the structures then becomes evident.”
From Artificial Intelligence Driving Materials Discovery? Perspective on the Article: Scaling Deep Learning for Materials Discovery (2024) · cites this paper as [24]
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Krause, L., Herbst-Irmer, R., Sheldrick, G. M., & Stalke, D. (2015) · Journal of Applied Crystallography · doi:10.1107/s1600576714022985 · Cited by 4,983
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Cheetham, A. K., & Seshadri, R. (2024) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c00643 · Cited by 191
Metadata
- Authors
- Kutahyali Aslani, C., Breton, L. S., Klepov, V. V., & zur Loye, H.-C.
- Affiliations
- Department of Chemistry and Biochemistry
- University of South Carolina (US)
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2021
- Volume
- 50
- Issue
- 5
- Pages
- 1683-1689
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W3119991521
- Cited by
- 16
- References
- 1
- Citations by year
- 2026: 3 · 2025: 1 · 2024: 3 · 2023: 5 · 2022: 3 · 2021: 1
- FWCI
- 0.75
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Dalton Transactions (publishedVersion)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Basic Energy Sciences (DE-SC0018739)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Crystal Structures and Properties
- Physical Sciences › Chemistry › Inorganic Chemistry › Inorganic Chemistry and Materials
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence Properties of Advanced Materials
- Keywords
- crystal structure, monoclinic P21/n, C2/c space group, crystal growth, optical band gap, fluorescence
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