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Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide
Abstract
A γ-carboxylation of α-CF 3 alkenes with CO 2 using platinum plate as both working cathode and nonsacrificial anode has been developed.
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“Defluorination of fluoroolefins with replacement by carbon dioxide was shown to be carried out in good yield by copper catalysts (Gao et al., 2020).”
From Nothing lasts forever: understanding microbial biodegradation of polyfluorinated compounds and perfluorinated alkyl substances (2022) · cites this paper as Gao et al., 2020
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Metadata
- Authors
- Gao, X.-T., Zhang, Z., Wang, X., Tian, J.-S., Xie, S.-L., Zhou, F., & Zhou, J.
- Affiliations
- Shanghai Key Laboratory of Green Chemistry and Chemical Processes
- College of Chemistry
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2020
- Volume
- 11
- Issue
- 38
- Pages
- 10414-10420
- ISSN
- 2041-6520
- 2041-6539
- PMC
- PMC8162267
- Cited by
- 142
- References
- 103
- Language
- en
- Funders
- National Natural Science Foundation of China (21871090)
- Fundamental Research Funds for the Central Universities
- Ministry of Education of the People's Republic of China
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