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Universal quenching of common fluorescent probes by water and alcohols
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Overtones and combinations of O–H vibrations in the solvent efficiently quench red-emitting fluorophores by resonant energy transfer.
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“In the case of polymethine dyes, water can reduce Φfl by up to threefold.76”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [76]
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Metadata
- Authors
- Maillard, J., Klehs, K., Rumble, C., Vauthey, E., Heilemann, M., & Fürstenberg, A.
- Affiliations
- University of Geneva (CH)
- Goethe University Frankfurt (DE)
- Corresponding author
- Heilemann, Mike
- Fürstenberg, Alexandre
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2021
- Volume
- 12
- Issue
- 4
- Pages
- 1352-1362
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- PMC
- PMC8179231
- OpenAlex
- W3109218211
- Cited by
- 306
- References
- 90
- Citations by year
- 2026: 57 · 2025: 67 · 2024: 75 · 2023: 57 · 2022: 35 · 2021: 15
- FWCI
- 15.55
- Type
- journal article
- Language
- en
- Open access
- diamond
- doi.org
- Licence
- Locations
- Chemical Science (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Archive ouverte UNIGE (University of Geneva) (publishedVersion, other-oa)
- Archive ouverte UNIGE (University of Geneva) (submittedVersion, cc-by)
- Funders
- Université de Genève
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Physical Sciences › Chemistry › Spectroscopy › Molecular Sensors and Ion Detection
- Keywords
- fluorescence quenching, red-emitting fluorophores, water, alcohol chemistry, solvent effects, vibrational overtones, combination bands, resonance energy transfer, fluorescent probes
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