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Cited by 119Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research

Understanding the active formation of a cathode–electrolyte interphase (CEI) layer with energy level band bending for lithium-ion batteries

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Kim, Taehoon, Ono, Luis K., Qi, Yabing·2023·Journal of Materials Chemistry A
DOI 10.1039/d2ta07565b
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Abstract

Downward band bending induced by the migration of positive charges (Li + ) to the cathode–electrolyte interphase (CEI) layer after electrochemical cycling.

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  • The formation of the cathode-electrolyte interphase (CEI) between the cathode and the electrolyte is crucial for the stability of lithium-ion batteries, especially for low-temperature cycling.

    “The formation of the cathode–electrolyte interphase (CEI) between the cathode and the electrolyte is crucial for the stability of LiB, especially for LT cycling39,40,41.”

    From High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries (2025) · cites this paper as [39]

    The Conclusions link formation of an unstable CEI layer to capacity decay, supporting the importance of the cathode–electrolyte interphase for battery stability. The Results and discussion do not establish the claim about low-temperature cycling: their “RT” condition means a rate capability test with changing current rates, not low-temperature cycling. Page numbers are unavailable in our copy. (LLM, conf=0.88)

    Experimental — accuracy not yet measured

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Research works printed but not linked: 51

  1. M. Armand and J. M. Tarascon, Nature, 2008, 451, 652-657.
  2. D. Larcher and J.-M. Tarascon, Nat. Chem., 2015, 7, 19-29.
  3. T. Kim, W. Song, D. Y. Son, L. K. Ono and Y. Qi, J. Mater. Chem. A, 2019, 7, 2942-2964.
  4. A. Manthiram, J. C. Knight, S. T. Myung, S. M. Oh and Y. K. Sun, Adv. Energy Mater., 2016, 6, 1501010.
  5. N. Nitta, F. Wu, J. T. Lee and G. Yushin, Mater. Today, 2014, 18, 252-264.
  6. W. Lee, S. Muhammad, T. Kim, H. Kim, E. Lee, M. Jeong, S. Son, J. H. Ryou and W. S. Yoon, Adv. Energy Mater., 2018, 8(4), 1701788.
  7. M. Dixit, M. Kosa, O. S. Lavi, B. Markovsky, D. Aurbach and D. T. Major, Phys. Chem. Chem. Phys., 2016, 18, 6799-6812.
  8. K. Luo, M. R. Roberts, R. Hao, N. Guerrini, D. M. Pickup, Y.-S. Liu, K. Edström, J. Guo, A. V. Chadwick, L. C. Duda and P. G. Bruce, Nat. Chem., 2016, 8, 1-17.
  9. Z. Li, N. a. Chernova, M. Roppolo, S. Upreti, C. Petersburg, F. M. Alamgir and M. S. Whittingham, J. Electrochem. Soc., 2011, 158, A516.
  10. S.-H. Kang, P. Kempgens, S. Greenbaum, a. J. Kropf, K. Amine and M. M. Thackeray, J. Mater. Chem., 2007, 17, 2069.
  11. A. N. Mansour, L. Croguennec and C. Delmas, Electrochem. Solid-State Lett., 2005, 8, A544.
  12. J. R. Croy, M. Balasubramanian, D. Kim, S.-H. Kang and M. M. Thackeray, Chem. Mater., 2011, 23, 5415-5424.
  13. S. M. Bak, E. Hu, Y. Zhou, X. Yu, S. D. Senanayake, S. J. Cho, K. B. Kim, K. Y. Chung, X. Q. Yang and K. W. Nam, ACS Appl. Mater. Interfaces, 2014, 6, 22594-22601.
  14. D. Y. W. Yu and K. Yanagida, J. Electrochem. Soc., 2011, 158, A1015.
  15. S.-T. Myung, F. Maglia, K.-J. Park, C. S. Yoon, P. Lamp, S.-J. Kim and Y.-K. Sun, ACS Energy Lett., 2017, 2, 196-223.
  16. S.-T. Myung, K.-S. Lee, Y.-K. Sun and H. Yashiro, J. Power Sources, 2011, 196, 7039-7043.
  17. L. Li, L. Wang, X. Zhang, M. Xie, F. Wu and R. Chen, ACS Appl. Mater. Interfaces, 2015, 7, 21939-21947.
  18. J. P. Pender, G. Jha, D. H. Youn, J. M. Ziegler, I. Andoni, E. J. Choi, A. Heller, B. S. Dunn, P. S. Weiss, R. M. Penner and C. B. Mullins, ACS Nano, 2020, 14, 1243-1295.
  19. T. Li, X. Z. Yuan, L. Zhang, D. Song, K. Shi and C. Bock, Electrochem. Energy Rev., 2020, 3, 43-80.
  20. M. D. Radin, S. Hy, M. Sina, C. Fang, H. Liu, J. Vinckeviciute, M. Zhang, M. S. Whittingham, Y. S. Meng and A. Van der Ven, Adv. Energy Mater., 2017, 7, 1602888.
  21. W. Liu, P. Oh, X. Liu, M.-J. Lee, W. Cho, S. Chae, Y. Kim and J. Cho, Angew. Chem., Int. Ed., 2015, 54, 4440-4457.
  22. S.-K. Jung, H. Gwon, J. Hong, K.-Y. Park, D.-H. Seo, H. Kim, J. Hyun, W. Yang and K. Kang, Adv. Energy Mater., 2014, 4, 1300787.
  23. A. Manthiram, Nat. Commun., 2020, 11, 1-9.
  24. S. Hwang, W. Chang, S. M. Kim, D. Su, D. H. Kim, J. Y. Lee, K. Y. Chung and E. a Stach, Chem. Mater., 2014, 26, 1084- 1092.
  25. W. Li, A. Dolocan, P. Oh, H. Celio, S. Park, J. Cho and A. Manthiram, Nat. Commun., 2017, 8, 14589.
  26. W. Zhao, J. Zheng, L. Zou, H. Jia, B. Liu, H. Wang, M. H. Engelhard, C. Wang, W. Xu, Y. Yang and J. G. Zhang, Adv. Energy Mater., 2018, 8, 1-9.
  27. M. Gauthier, T. J. Carney, A. Grimaud, L. Giordano, N. Pour, H.-H. Chang, D. P. Fenning, S. F. Lux, O. Paschos, C. Bauer, F. Maglia, S. Lupart, P. Lamp and Y. Shao-Horn, J. Phys. Chem. Lett., 2015, 6, 4653-4672.
  28. R. Hausbrand, G. Cherkashinin, H. Ehrenberg, M. Gröting, K. Albe, C. Hess and W. Jaegermann, Mater. Sci. Eng., B, 2015, 192, 3-25.
  29. G. Cherkashinin, M. Motzko, N. Schulz, T. Späth and W. Jaegermann, Chem. Mater., 2015, 27, 2875-2887.
  30. M. Weiss, F. J. Simon, M. R. Busche, T. Nakamura, D. Schröder, F. H. Richter and J. Janek, Electrochem. Energy Rev., 2020, 3, 221-238.
  31. T. R. Jow, S. A. Delp, J. L. Allen, J.-P. Jones and M. C. Smart, J. Electrochem. Soc., 2018, 165, A361-A367.
  32. P. M. Chekushkin, I. S. Merenkov, V. S. Smirnov, S. A. Kislenko and V. A. Nikitina, Electrochim. Acta, 2021, 372, 137843.
  33. I. Takahashi, H. Kiuchi, A. Ohma, T. Fukunaga and E. Matsubara, J. Phys. Chem. C, 2020, 124, 9243-9248.
  34. D. Becker, G. Cherkashinin, R. Hausbrand and W. Jaegermann, J. Phys. Chem. C, 2014, 118, 962-967.
  35. R. Hausbrand, D. Becker and W. Jaegermann, Prog. Solid State Chem., 2014, 42, 175-183.
  36. L. Qiu, S. He, L. K. Ono and Y. Qi, Adv. Energy Mater., 2020, 10, 1902726.
  37. J. Zhi, S. Li, M. Han, Y. Lou and P. Chen, Adv. Energy Mater., 2018, 8, 1-11.
  38. Y. Li, L. Cui, C. Tan, X. Fan, Q. Pan, Y. Chu, S. Hu, F. Zheng, H. Wang and Q. Li, Chem. Eng. J., 2022, 430, 132985.
  39. D. Kim, J. M. Lim, Y. G. Lim, J. S. Yu, M. S. Park, M. Cho and K. Cho, Chem. Mater., 2015, 27, 6450-6456.
  40. Y. M. Lee, K. M. Nam, E. H. Hwang, Y. G. Kwon, D. H. Kang, S. S. Kim and S. W. Song, J. Phys. Chem. C, 2014, 118, 10631- 10639.
  41. J. Yuan, J. Wen, J. Zhang, D. Chen and D. Zhang, Electrochim. Acta, 2017, 230, 116-122.
  42. T. Eriksson, A. M. Andersson, C. Gejke, T. Gustafsson and J. O. Thomas, Langmuir, 2002, 18, 3609-3619.
  43. K. Edstr, T. Gustafsson and J. O. Thomas, Electrochim. Acta, 2004, 50, 397-403.
  44. D. T. Nguyen, J. Kang, K. M. Nam, Y. Paik and S. W. Song, J. Power Sources, 2016, 303, 150-158.
  45. N. Tran, L. Croguennec, M. Ménétrier, F. Weill, P. Biensan, C. Jordy and C. Delmas, Chem. Mater., 2008, 20, 4815-4825.
  46. M. Noh and J. Cho, J. Electrochem. Soc., 2013, 160, A105-A111.
  47. T. Eriksson, A. M. Andersson, A. G. Bishop, C. Gejke, T. Gustafsson and J. O. Thomas, J. Electrochem. Soc., 2002, 149, A69.
  48. A. M. Andersson, D. P. Abraham, R. Haasch, S. MacLaren, J. Liu and K. Amine, J. Electrochem. Soc., 2002, 149, A1358.
  49. J. A. Gilbert, I. A. Shkrob and D. P. Abraham, J. Electrochem. Soc., 2017, 164, A389-A399.
  50. W. Hua, B. Schwarz, R. Azmi, M. Müller, M. S. Dewi Darma, M. Knapp, A. Senyshyn, M. Heere, A. Missyul, L. Simonelli, J. R. Binder, S. Indris and H. Ehrenberg, Nano Energy, 2020, 78, 105231.
  51. D. Mohanty and H. Gabrisch, J. Power Sources, 2012, 220, 405-412.

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Sorted by citations

Authors
Kim, T., Ono, L. K., & Qi, Y.
Affiliations
Okinawa Institute of Science and Technology Graduate University (JP)
Corresponding author
  • Kim, Taehoon
  • Qi, Yabing
ORCID
Venue
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Published
2023
Volume
11
Issue
1
Pages
221-231
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
DOI
10.1039/d2ta07565b
OpenAlex
W4312082265
Cited by
119
References
0
Citations by year
2026: 46 · 2025: 50 · 2024: 18 · 2023: 5
FWCI
4.99
Type
journal article
Language
en
Open access
Licence
Locations
  • Journal of Materials Chemistry A (publishedVersion, cc-by-nc)
  • Institutional Repositories DataBase (IRDB) (submittedVersion, cc-by-nc-nd)
  • Okinawa Institute of Science and Technology Graduate University (Okinawa Institute of Science and Technology Graduate University) (submittedVersion, cc-by-nc-nd)
Funders
  • Okinawa Institute of Science and Technology Graduate University
  • National Research Foundation of Korea (NRF-2021R1F1A1051969)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
  • Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
Keywords
cathode electrolyte interphase, band bending, lithium-ion batteries, lithium ion migration, solid electrolyte interphase formation, electrochemical cycling, lithium metal anode

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