Graphene triggered catalytic attack on plastic waste produces graphitic shell encapsulation on cobalt nanoparticles for ferromagnetism and stable Li + ion storage
Open accessAbstract
Plastic wastes produced graphitic carbon shell encapsulation on cobalt nanoparticles and the derived composite materials showed ferromagnetism and superior Li + ion storage of 377 mA h g –1 (Co-GNP-ZipC) and 509 mA h g –1 (Co-GNP-FmC) at the 250 th cycle.
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Palanisamy and colleagues achieved ultra-rapid conversion (2 min) of waste polyethylene and polystyrene via microwave catalytic technology, preparing core-shell composites of graphite-encapsulated cobalt nanoparticles (Co-GNP).
“Differing from hierarchical pores, Palanisamy and colleagues achieved ultra-rapid conversion (2 min) of waste polyethylene and polystyrene via microwave catalytic technology, preparing coreshell composites of graphite-encapsulated cobalt nanoparticles (Co-GNP) [125] .”
From Functional carbon materials from waste plastics: synthesis and applications (2025) · cites this paper as [125]
Waste plastic-derived Co-GNP-ZipC and Co-GNP-FmC retained reversible capacities of 377 and 509 mAh/g (coulombic efficiency ~101%) at the 250th cycle, far superior to pristine Co-GNP (<1 mAh/g).
“Cycling performance showed that the waste plastic-derived Co-GNP-ZipC and Co-GNP-FmC retained reversible capacities of 377 and 509 mAh/g (coulombic efficiency ~101%) at the 250 th cycle, far superior to the pristine Co-GNP (< 1 mAh/g).”
From Functional carbon materials from waste plastics: synthesis and applications (2025) · cites this paper as [125]
The graphitic shell effectively isolates the cobalt core from the electrolyte, suppressing side reactions and mitigating volume strain, thereby significantly enhancing lithium storage stability.
“The graphitic shell effectively isolates the cobalt core from the electrolyte, suppressing side reactions and mitigating volume strain, thereby significantly enhancing lithium storage stability.”
From Functional carbon materials from waste plastics: synthesis and applications (2025) · cites this paper as [125]
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References 70 · Cited by 5
- Authors
- Palanisamy, M., Perumal, R., Zhang, D., Wang, H., Maximova, O., Rokhinson, L., & Pol, V. G.
- Affiliations
- Purdue University West Lafayette (US)
- Department of Mechanical Engineering, SRM TRP Engineering College, Tiruchirappalli, Tamilnadu, 621105, India
- Corresponding author
- Palanisamy, Manikandan
- Pol, Vilas G.
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2024
- Volume
- 12
- Issue
- 30
- Pages
- 19081-19093
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W4400463584
- Cited by
- 5
- References
- 70
- Citations by year
- 2026: 2 · 2025: 3
- FWCI
- 0.52
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Journal of Materials Chemistry A (publishedVersion, cc-by)
- Funders
- Davidson School of Chemical Engineering, Purdue University
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Keywords
- plastic waste, graphene, cobalt nanoparticles, graphitic carbon shell, ferromagnetism, lithium-ion storage, lithium-ion battery anodes, waste-derived materials, composite materials
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