The DOI matches its Crossref record.
Confirmation of the surface structures of goethite (α-FeOOH) and phosphated goethite by infrared spectroscopy
Abstract
The infrared absorption spectrum of phosphate adsorbed on α-FeOOD and α-FeOOH establishes the presence of binuclear (FeO)2PO. OH groups, bridging adjacent Fe3+ ions on (100) faces of the crystals. Examination of D2O-exchanged surfaces shows the predicted three species of OD on the goethite surface, two on fluoridated goethite, and four (including POD) on phosphated goethite. The spectrum of adsorbed pyridine indicates that both goethite and phosphated goethite have Lewis acid sites on edge faces only; neither exhibit Brönsted acidity. These observations confirm a proposed model of the (100) face.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Arai, Y., & Sparks, D. L. (2001) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2001.7773 · Cited by 757
AN INVESTIGATION OF ARSENATE AND ARSENITE BONDING STRUCTURES ON GOETHITE BY FTIR
Sun, X., & Doner, H. E. (1996) · Soil Science · doi:10.1097/00010694-199612000-00006 · Cited by 329
ADSORPTION ON HYDROUS OXIDES. III. FULVIC ACID AND HUMIC ACID ON GOETHITE, GIBBSITE AND IMOGOLITE
PARFITT, R. L., FRASER, A. R., & FARMER, V. C. (1977) · Journal of Soil Science · doi:10.1111/j.1365-2389.1977.tb02237.x · Cited by 302
Self-citationVibrational spectroscopy of functional group chemistry and arsenate coordination in ettringite
Myneni, S. C. B., Traina, S. J., Waychunas, G. A., & Logan, T. J. (1998) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(98)00221-x · Cited by 295
Reaction of Anions and Cations with Variable-Charge Soils
Barrow, N. J. (1986) · Advances in Agronomy · doi:10.1016/s0065-2113(08)60676-8 · Cited by 257
Metadata
- Authors
- Parfitt, R. L., Russell, J. D., & Farmer, V. C.
- Venue
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1976
- Volume
- 72
- Issue
- 0
- Pages
- 1082
- ISSN
- 0300-9599 (ISSN-L)
- OpenAlex
- W2040937868
- Cited by
- 169
- References
- 0
- FWCI
- 7.67
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Confirmation of the surface structures of goethite (α-FeOOH) and phosphated goethite by infrared spectroscopy. https://app.cochat.ai/papers/10.1039/f19767201082
- The paper
- Parfitt, R. L., Russell, J. D., & Farmer, V. C. (1976). Confirmation of the surface structures of goethite (α-FeOOH) and phosphated goethite by infrared spectroscopy. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. https://doi.org/10.1039/f19767201082
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
