The DOI matches its Crossref record.
The thermodynamics of solvation of ions. Part 2.—The enthalpy of hydration at 298.15 K
Abstract
So-called ‘absolute’ standard molar enthalpies of hydration of individual ions at 298.15 K have been obtained from the conventional data by means of the widely employed TATB extrathermodynamic assumption, i.e. that ΔhydH°[(C6H5)4As+]=ΔhydH°[(C6H5)4P+]=ΔhydH°[B(C6H5)–4]. This is possible by the evaluation of the standard molar enthalpies of hydration of salts involving the tetraphenyl ions with suitable counter-ions from their lattice enthalpies and heats of solution and appropriate combinations of these data. The resulting value of the standard molar enthalpy of hydration of the hydrogen ion, ΔhydH°[H+]=–1103 ± 7 kJ mol–1, agrees with the values obtained by other reliable methods. The values of ΔhydH° on this basis of numerous ions are tabulated.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Citations
Cited by
Sorted by citations
Items 201–247 of 247
周福录, & Carbone, P. (2026) · Faraday Discussions · doi:10.1039/d5fd00147a · Cited by 2
Assessing the potential of zero charge in ab initio molecular dynamics simulations
Hagopian, A., Koper, M. T. M., & Doblhoff-Dier, K. (2026) · The Journal of Chemical Physics · doi:10.1063/5.0322322 · Cited by 2
Theoretical Study on Co3+ in Aqueous Solution in Terms of ABEEM/MM Model
Guan, Q., & Yang, Z. (2007) · Chinese Journal of Chemistry · doi:10.1002/cjoc.200790136 · Cited by 2
Heat-induced phase separation of alkali chloride–HFIP–water mixtures
Takamuku, T., Kouda, Y., & Shimomura, T. (2013) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2013.03.001 · Cited by 2
Bleam, W. (2016) · Elsevier eBooks · doi:10.1016/b978-0-12-804178-9.00004-5 · Cited by 2
Venter, P. B. (2025) · Molecules · doi:10.3390/molecules30091885 · Cited by 1
“…the interior of the droplet for complete solvation [16,17]. cannot be made due to differences in their conjugate base species, which In the context of this study, the solvation enthalpy of NH 4+ is − 329 kJ/mol, while that of H 3 O + is signi fi cantly more negative at − 1150 ± 0.9 kJ/mol [18].”
InfluentialShah, Y., Meech, S. R., & Heisler, I. A. (2025) · ACS Omega · doi:10.1021/acsomega.5c09879 · Cited by 1
Lehmann, M., Jameel, F., & Kaupp, M. (2026) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.6c00886 · Cited by 1
“For example, the enthalpy contributions involve lattice energies of the corresponding salts, 119 which may not be reliable.”
Anion Transport and Selectivity in Ordered Nanoporous Polymers with 1 nm Scale Charged Pores
Johnson, C. P., Ball, R., Zhang, L., Oh, S. M., Hopkins, R., Culley, K. E., Ali, A. S., Granite, J. E., Patel, A. J., Anna, J. M., et al. (2026) · ACS Nano · doi:10.1021/acsnano.6c04846 · Cited by 1
Reprint of: The enthalpy of formation of gaseous tetra-n-propylammonium cations
Marcus, Y. (2014) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2014.03.019 · Cited by 1
Self-citationDisplacement of Cu(II) by Ag(I) in Solvated Metal Sulfides. A DFT and AIM Computational Study
Kramer, J. R., Werstiuk, N. H., & Ni, B. (2005) · The Journal of Physical Chemistry A · doi:10.1021/jp0543375 · Cited by 1
Badshah, S. L., & Airoldi, C. (2014) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2014.03.010 · Cited by 1
Zhang, Z., Zhang, Q., Tian, F., Guan, W., & Yang, J.-Z. (2014) · Journal of Chemical & Engineering Data · doi:10.1021/je4010432 · Cited by 1
Kuncoro, H. S., Sakaue, M., & Kasai, H. (2019) · Journal of Physics Communications · doi:10.1088/2399-6528/ab3d8a · Cited by 1
Marcus, Y. (2012) · Springer eBooks · doi:10.1007/978-94-007-4647-3_2 · Cited by 1
Self-citationAhmed, M., Inoue, K., Nihonyanagi, S., & Tahara, T. (2020) · Angewandte Chemie · doi:10.1002/ange.202002368 · Cited by 1
Electrokinetic comparison of CaF2 and AgCl from a MDS perspective
Liu, W., Miller, J. D., Sun, W., & Hu, Y. (2023) · Minerals Engineering · doi:10.1016/j.mineng.2023.108118 · Cited by 1
Kawamata, Y., Iiyama, T., Futamura, R., Otsuka, H., & Kaneko, K. (2024) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.4c01944 · Cited by 1
Dybczyński, R., & Kulisa, K. (2018) · Separation Science and Technology · doi:10.1080/01496395.2018.1443140 · Cited by 1
“Taking the standard molar enthalpies published by Marcus,([27]) the predicted order of affinity of univalent ions to anion exchanger should be F< BrO3 − < Cl < Br < NO3 − < SCN< ClO3 ≪ I< ClO4.”
BackgroundMolecular Modeling of Structure and Reactivity at the Metal/Environment Interface
Taylor, C. D. (2015) · doi:10.1002/9781119057666.ch2 · Cited by 1
Incredible internal strains within a biogenic single crystal viewed by X-ray diffraction tomographyPreprint
Seknazi, E., Zaslansky, P., Katsman, A., Villanova, J., & Pokroy, B. (2020) · bioRxiv (Cold Spring Harbor Laboratory) · doi:10.1101/2020.11.16.384610 · Cited by 1
Griffith, W. P., Robinson, S. D., & Swars, K. (1989) · Springer eBooks · doi:10.1007/978-3-662-09188-3_4
Characteristics of the Ca 2+ Ion
Horrocks, W. D. (1993) · Inorganic reactions and methods · doi:10.1002/9780470145319.ch206
Thermochemistry of Concentrated Solutions of Bu4NI in Acetonitrile at 233-323 K
Kinchin, A. N., & Kolker, A. M. (2003) · Russian Journal of General Chemistry · doi:10.1023/a:1024719416802
Zhang, L., Di, Y., & Dou, J. (2012) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2012.07.026
Lu, D.-F., Di, Y., & Dou, J. (2013) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2012.12.023
Thermodynamics of ions of chromic and thiocyanic acids: solvation in the ethanol–water system
Tsurko, E. N., Rubtsov, V. I., & Alexandrov, V. V. (1996) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9969201345
Kariev, A. M., & Овчинников, А. А. (1991) · International Journal of Quantum Chemistry · doi:10.1002/qua.560390203
Jenkins, H. D. B. (1992) · Zeitschrift für Physikalische Chemie · doi:10.1524/zpch.1992.177.part_2.157
Síntese e Propriedades de Surfactantes Di-Aniónicos: interacção com iões trivalentes
Costa, P. B. A. (2011) · Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT)
Dyer, K. M., Perkyns, J. S., & Pettitt, B. M. (2016) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/28/41/414006
Smart polymer composite materials for water processing
Ou, R. (2017) · Figshare · doi:10.4225/03/598bbcb7056da
Sadri, F., Yang, Z., & Ghahreman, A. (2018) · The minerals, metals & materials series · doi:10.1007/978-3-319-95022-8_222
(2012) · Elsevier eBooks · doi:10.1016/b978-0-12-415797-2.00011-x
Molecular Dynamic Modeling of Pertechnate Ion in Aqueous Solution
Volobuiev, M., Korohodska, A. N., Kramarenko, A. V., Semkina, O., & Kolesnyk, Y. (2025) · Kharkov University Bulletin Chemical Series · doi:10.26565/2220-637x-2025-45-03
Xiong, X., Uhlig, F., Pietsch, I., Basheer, N., Rosenfeldt, S., Papastavrou, G., Peiffer, S., Lueders, T., & Breu, J. (2026) · Applied Clay Science · doi:10.1016/j.clay.2026.108233
Le, V. T. C., Tran, H. M., & Bui, N. T. (2026) · Sustainability Science and Technology · doi:10.1088/2977-3504/ae6455
“[ 24, 63, 85, 92] All thermodynamic terms are in 298.15 K.”
InfluentialLee, Y., Kim, J.-S., & Kim, J.-D. (2026) · Nuclear Engineering and Technology · doi:10.1016/j.net.2026.104406
Lu, P.-Y., Ha, T.-H., Choi, A. E. S., & Lu, M. (2026) · Process Safety and Environmental Protection · doi:10.1016/j.psep.2026.109114
Tatini, D., Acar, M., Baglioni, M., Tamasi, G., Rossi, C., & Nostro, P. L. (2026) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2026.125616
Silva, M. D. D. O., Aguiar, C., Coelho, Y. L., Lemes, N. H. T., & Virtuoso, L. S. (2026) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.6c00210
Silva, G. M., Liang, X., & Kontogeorgis, G. M. (2026) · The Journal of Chemical Physics · doi:10.1063/5.0333864
Metalloprotein-Inspired UiO-66 Traps for Heavy Metal Removal: An Exploration of Interfacial Dynamics
Rajendran, H. K., Deen, M. A., & Selvaraju, N. (2026) · Langmuir · doi:10.1021/acs.langmuir.6c03324
Blei, M., Waurick, L., Drobot, B., Brühlmann, S. A., Duchemin, C., Mamis, E., Inzamam, M., Storà, T., Audouin, N., Sounalet, T., et al. (2026) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6c01646
Carrick, E., & McManus, J. J. (2026) · Biomacromolecules · doi:10.1021/acs.biomac.6c01474
Metadata
- Authors
- Marcus, Y.
- Corresponding author
- Marcus, Yizhak
- ORCID
- Marcus, Yizhak
- Venue
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1987
- Volume
- 83
- Issue
- 2
- Pages
- 339
- ISSN
- 0300-9599 (ISSN-L)
- OpenAlex
- W2017026866
- Cited by
- 247
- References
- 0
- Citations by year
- 2026: 17 · 2025: 7 · 2024: 6 · 2023: 7 · 2022: 7 · 2021: 7 · 2020: 8 · 2019: 10 · 2018: 16 · 2017: 10 · 2016: 14 · 2015: 8 · 2014: 13 · 2013: 8 · 2012: 9
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Thermodynamic properties of mixtures
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Keywords
- ion hydration, hydration enthalpy, tetraphenylborate, tetraphenylphosphonium, lattice enthalpy, enthalpy of solution, solvation thermodynamics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
