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Ionic conductivity of lanthanoid silicates, Ln10(SiO4)6O3(Ln = La, Nd, Sm, Gd, Dy, Y, Ho, Er and Yb)
Abstract
Ionic conductivities have been investigated for lanthanoid silicates of the Ln10(SiO4)6O3 solid solution series and related compounds. The activation energy and conductivity at 500 °C were estimated to be 69 kJ mol–1 and 1.8 × 10–4 S cm–1 for La10(SiO4)6O3 and 71 kJ mol–1 and 1.5 × 10–4 S cm–1 for Nd10(SiO4)6O3. The a and c lattice constants of the hexagonal phase decreased with decreasing radius of the Ln3+ ion for Ln10(SiO4)6O3(Ln = La, Nd, Sm, Gd and Dy). The activation energy increased and the conductivity decreased when Ln3+ ions with smaller ionic radii were used. The sole carrier in these materials is the O2– ion.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Ionic Conductivity of Solid Electrolytes Based on Lithium Titanium Phosphate
Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N., & Adachi, G. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086597 · Cited by 923
Self-citationIonic conductivity of Li4SiO4 solid solutions in the system Li2O-Al2O3-SiO2
Jackowska, K., & West, A. R. (1983) · Journal of Materials Science · doi:10.1007/bf00541842 · Cited by 75
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Metadata
- Authors
- Nakayama, S., Kageyama, T., Aono, H., & Sadaoka, Y.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1995
- Volume
- 5
- Issue
- 11
- Pages
- 1801
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2122162157
- Cited by
- 398
- References
- 3
- FWCI
- 0.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Ionic conductivity of lanthanoid silicates, Ln10(SiO4)6O3(Ln = La, Nd, Sm, Gd, Dy, Y, Ho, Er and Yb). https://app.cochat.ai/papers/10.1039/jm9950501801
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- Nakayama, S., Kageyama, T., Aono, H., & Sadaoka, Y. (1995). Ionic conductivity of lanthanoid silicates, Ln10(SiO4)6O3(Ln = La, Nd, Sm, Gd, Dy, Y, Ho, Er and Yb). Journal of Materials Chemistry. https://doi.org/10.1039/jm9950501801
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