The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
The production of HCN dimer and more complex oligomers in dense interstellar clouds
Open accessAbstract
Using quantum chemical and kinetic techniques, we show that the reaction between two HCN molecules under interstellar conditions cannot lead efficiently to a dimer of this species (H2C2N2), whatever its structure. If the dimerization reaction does not occur efficiently, then it is impossible to synthesize detectable abundances of the pre-biotic HCN oligomer adenine (H5C5N5) in the interstellar medium via successive neutral-neutral reactions between HCN and its dimer, trimer, and tetramer.
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“However, it has been found that interstellar gas-phase production routes are incapable of producing significant amounts of HCN [128,129], in spite of its detection.”
From The future of quantum biology (2018) · cites this paper as [128]
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Cites
Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
A Rapidly Convergent Descent Method for Minimization
Fletcher, R., & Powell, M. J. D. (1963) · The Computer Journal · doi:10.1093/comjnl/6.2.163 · Cited by 4,620
Mechanism of Synthesis of Adenine from Hydrogen Cyanide under Possible Primitive Earth Conditions
ORÓ, J. (1961) · Nature · doi:10.1038/1911193a0 · Cited by 396
Lee, H.-H., Bettens, R. P. A., & Herbst, E. (1996) · Astronomy & Astrophysics Supplement Series · doi:10.1051/aas:1996232 · Cited by 246
Self-citationThe vibrational ground state rotational spectroscopic constants and structure of the HCN dimer
Buxton, L. W., Campbell, E. J., & Flygare, W. H. (1981) · Chemical Physics · doi:10.1016/0301-0104(81)80161-9 · Cited by 130
Giauque, W. F., & Ruehrwein, R. A. (1939) · Journal of the American Chemical Society · doi:10.1021/ja01265a017 · Cited by 93
Frisch, M. J., Trucks, G. W., & Cheeseman, J. R. (1996) · Theoretical and computational chemistry · doi:10.1016/s1380-7323(96)80100-2 · Cited by 57
Integrated intensities for some infrared absorption bands of HCN
Smith, I. W. M. (1981) · Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics · doi:10.1039/f29817702357 · Cited by 52
Self-citationBates, D. R., & Herbst, E. (1988) · Astrophysics and space science library · doi:10.1007/978-94-009-3007-0_2 · Cited by 43
Self-citationPossible precursors in HCN oligomerization
Clemmons, J. H., Jasien, P. G., & Dykstra, C. E. (1983) · Molecular Physics · doi:10.1080/00268978300100461 · Cited by 30
A search for the interstellar HCN dimer
Schenewerk, M. S., Jewell, P. R., Snyder, L. E., Buxton, L. W., Campbell, E. J., & Flygare, W. H. (1985) · The Astrophysical Journal · doi:10.1086/163439 · Cited by 5
Research works printed but not linked: 2
- Chakrabarti, 2000, A&A, 354, L6
- Chakrabarti, 2000, Ind. J. Phys., 74B, 97
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Marais, A., Adams, B., Ringsmuth, A. K., Ferretti, M., Gruber, J. M., Hendrikx, R., Schuld, M., Smith, S. L., Sinayskiy, I., Krüger, T. P. J., et al. (2018) · Journal of The Royal Society Interface · doi:10.1098/rsif.2018.0640 · Cited by 274
Genetics first or metabolism first? The formamide clue
Saladino, R., Botta, G., Pino, S., Costanzo, G., & Di Mauro, E. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35066a · Cited by 215
Photoion mass spectrometry of adenine, thymine and uracil in the 6–22eV photon energy range
Jochims, H. ‐., Schwell, M., Baumgärtel, H. G., & Leach, S. (2005) · Chemical Physics · doi:10.1016/j.chemphys.2005.03.008 · Cited by 192
The neutral photochemistry of nitriles, amines and imines in the atmosphere of Titan
Loison, J., Hébrard, É., Dobrijévic, M., Hickson, K. M., Caralp, F., Hue, V., Gronoff, G., Vénot, O., & Bénilan, Y. (2014) · Icarus · doi:10.1016/j.icarus.2014.09.039 · Cited by 168
DETECTION OF E-CYANOMETHANIMINE TOWARD SAGITTARIUS B2(N) IN THE GREEN BANK TELESCOPE PRIMOS SURVEY
Zaleski, D. P., Seifert, N. A., Steber, A. L., Muckle, M. T., Loomis, R. A., Corby, J. F., Martinez, O., Crabtree, K. N., Jewell, P. R., Hollis, J. M., et al. (2013) · The Astrophysical Journal · doi:10.1088/2041-8205/765/1/l10 · Cited by 133
Metadata
- Authors
- Smith, I. W. M., Talbi, D., & Herbst, E.
- Affiliations
- University of Birmingham (GB)
- Université Nice Sophia Antipolis (FR)
- The Ohio State University (US)
- Venue
- Astronomy & Astrophysics
- Publisher
- EDP Sciences
- Published
- 2001-04
- Volume
- 369
- Issue
- 2
- Pages
- 611-615
- ISSN
- 0004-6361 (ISSN-L)
- 1432-0746
- OpenAlex
- W2056587395
- Cited by
- 66
- References
- 11
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 4 · 2023: 2 · 2022: 1 · 2021: 3 · 2020: 2 · 2019: 2 · 2018: 6 · 2017: 4 · 2016: 6 · 2015: 5 · 2014: 3 · 2013: 2 · 2012: 4
- FWCI
- 0.20
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Astronomy and Astrophysics (publishedVersion)
- Springer Link (Chiba Institute of Technology) (submittedVersion)
- University of Birmingham Research Portal (University of Birmingham) (submittedVersion)
- Funders
- National Science Foundation
- Ohio State University
- Topics
- Physical Sciences › Physics and Astronomy › Astronomy and Astrophysics › Astrophysics and Star Formation Studies
- Physical Sciences › Physics and Astronomy › Astronomy and Astrophysics › Origins and Evolution of Life
- Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Astro and Planetary Science
- Keywords
- interstellar medium, dense interstellar clouds, prebiotic chemistry, adenine synthesis, neutral-neutral reactions, reaction kinetics, astrochemistry
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