Synthesis of a one-part geopolymer system for soil stabilizer using fly ash and volcanic ash
Open accessAbstract
A novel approach one-part geopolymer was employed to investigate the feasibility of enhancing the strength of in-situ soil for possible structural fill application in the construction industry. Geopolymer precursors such as fly ash and volcanic ash were utilized in this study for soil stabilization. The traditional geopolymer synthesis uses soluble alkali activators unlike in the case of ordinary Portland cement where only water is added to start the hydration process. This kind of synthesis is an impediment to geopolymer soil stabilizer commercial viability. Hence, solid alkali activators such as sodium silicate (SS), sodium hydroxide (SH), and sodium aluminate (SA) were explored. The influence of amount of fly ash (15% and 25%), addition of volcanic ash (0% and 12.5%), and ratio of alkali activator SS:SH:SA (50:50:0, 33:33:33, 50:20:30) were investigated. Samples cured for 28 days were tested for unconfined compressive strength (UCS). To evaluate the durability, sample yielding highest UCS was subjected to sulfuric acid resistance test for 28 days. Analytical techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), and scanning electron microscope/energy-dispersive X-ray spectroscopy (SEM/EDX) were performed to examine the elemental composition, mineralogical properties, and microstructure of the precursors and the geopolymer stabilized soil.
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Anne et al. strength value still does not comply with ASTM D 4609 (>0.8 MPa).
“However, the strength value still does not comply with the ASTM D 4609 standard [76], which requires a value greater than 0.8 MPa.”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
Section 3.2 (Unconfined compressive strength; page not provided) reports a maximum strength of 971 kPa, or 0.971 MPa—above the claimed 0.8 MPa threshold. Other tested formulations were below 0.8 MPa, but the paper does not say that all its strength values fail that threshold; it instead discusses a 75 kPa requirement from the National Structural Code of the Philippines, not ASTM D 4609. (LLM, conf=0.87)
Checked by a reasoning model — may be wrong.
Experimental — accuracy not yet measuredAddition of fly ash is one method to stabilize soil because fly ash is a pozzolan that can bind to minerals in soil and make the soil stable.
“The addition of fly ash is one of the methods to stabilize soil because fly ash is a pozzolan, in which it can bind to minerals in soil and make the soil stable”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
The Introduction describes fly ash as naturally pozzolanic, and §3.2 reports that increasing its proportion in an alkali-activated geopolymer mixture increased the compressive strength of stabilized soil. The paper does not establish the claim’s specific mechanism that fly ash binds to minerals in soil; the tested stabilizer also contained volcanic ash and alkali activators. Page numbers are not available for these passages. (LLM, conf=0.86)
Experimental — accuracy not yet measuredA longer curing time is required to reach optimum strength for Anne et al.
“Furthermore, a longer curing time is required to reach the optimum strength.”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
Section 3.3, Sulfuric acid resistance (page not provided), reports higher strength after 28 days of acid immersion and suggests that the additional time may have allowed further curing. It does not establish that longer curing is required to reach an optimum strength; the proposed effect of curing time is hedged. (LLM, conf=0.86)
Experimental — accuracy not yet measuredAddition of fly ash reduces swell shrinkage of soil and improves soil strength.
“so as to reduce the swell shrinkage of the soil and improve soil strength [41,42,44,46,54,69,70,71,72,73].”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
Section 3.2 (Unconfined compressive strength) reports that increasing fly ash increased the compressive strength of geopolymer-stabilized soil. The paper does not report a reduction in soil swelling or shrinkage; its soil characterization in Section 3.1.1 describes the soil as non-plastic silty sand. (LLM, conf=0.88)
Experimental — accuracy not yet measuredIn soil stabilization-based geopolymer, fly ash Class C and GGBFS are used as primary source material containing mostly high content in Si and Al that dissolve in alkali solution for geopolymerization.
“Commonly, in soil stabilization-based geopolymer, fly ash Class C and GGBFS are used as the primary source material containing mostly high content in silica (Si) and alumina (Al) that dissolve in alkali solution for geopolymerization in soil stabilization application [51,65,72,73,74].”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
The Introduction describes silica- and alumina-rich fly ash as a precursor for soil stabilization and explains that aluminosilicate feedstock dissolves in the presence of an alkali activator. However, §3.1.2 identifies this study’s fly ash as Class F, not Class C, and the paper uses volcanic ash rather than GGBFS. This source therefore does not support the claim’s specific pairing of Class C fly ash and GGBFS. (LLM, conf=0.88)
Experimental — accuracy not yet measured
Using NaOH solution in geopolymer synthesis causes low strength development if the molarity used is too high or too low.
“The obstacle of using NaOH solution in the geopolymer synthesis is the low strength development if the molarity used is too high or too low [71,72,74,80,92,94].”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
Section 3.2 (page not available) says a low proportion of sodium hydroxide in the alkali activator could yield low-strength stabilized soil. It does not test NaOH solution molarity or report that excessively high molarity lowers strength; within the ratios studied, it says strength tends to increase as the amount of sodium hydroxide increases. The Introduction describes this study as using solid activators rather than an activator solution. (LLM, conf=0.88)
Experimental — accuracy not yet measuredAnne et al. found strength increased as amount of fly ash increased (15% and 25%).
“According to the findings, strength increased as the amount of fly ash increased.”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
As solid-to-liquid ratio rose, geopolymers sample became less homogeneous due to limited amount of alkali activator.
“As the solid-to-liquid ratio rose, the geopolymers sample became less homogeneous due to the limited amount of alkali activator [48,51,72,74,78,93,94,98].”
From Potential of Soil Stabilization Using Ground Granulated Blast Furnace Slag (GGBFS) and Fly Ash via Geopolymerization Method: A Review (2022) · cites this paper as [72]
Section 3.2 discusses how alkali-activator composition affects strength, and section 3.5 describes a homogeneous structure in a soaked specimen. Neither passage links a rising solid-to-liquid ratio to reduced homogeneity or to insufficient activator. Searches for that ratio and the proposed explanation found no supporting passage in our copy; page numbers were not provided. (LLM, conf=0.72)
Experimental — accuracy not yet measured
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Cited by
Sorted by citations
Abdila, S. R., Abdullah, M. M. A. B., Ahmad, R., Burduhos Nergis, D. D., Rahim, S. Z. A., Omar, M. F., Sandu, A. V., Vizureanu, P., & Syafwandi (2022) · Materials · doi:10.3390/ma15010375 · Cited by 140 · see citing works
- Authors
- Tigue, A. A. S., Dungca, J. R., Hinode, H., Kurniawan, W., & Promentilla, M. A. B.
- Affiliations
- De La Salle University (PH)
- Tokyo Institute of Technology (JP)
- ORCID
- Venue
- MATEC Web of Conferences
- Publisher
- EDP Sciences
- Published
- 2018
- Volume
- 156
- Pages
- 05017
- ISSN
- 2261-236X (ISSN-L)
- OpenAlex
- W2789688807
- Cited by
- 21
- References
- 0
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 4 · 2023: 2 · 2022: 4 · 2021: 5 · 2018: 2
- FWCI
- 5.73
- Type
- conference paper
- Language
- en
- Open access
- diamond
- doi.org
- Licence
- Locations
- MATEC Web of Conferences (publishedVersion, cc-by)
- Springer Link (Chiba Institute of Technology) (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Tokyo Tech Research Repository (Tokyo Institute of Technology) (submittedVersion)
- Funders
- De La Salle University
- University Research Coordination Office, De La Salle University
- Japan Society for the Promotion of Science
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Engineering › Civil and Structural Engineering › Geotechnical Engineering and Soil Stabilization
- Physical Sciences › Engineering › Civil and Structural Engineering › Geotechnical and construction materials studies
- Keywords
- one-part geopolymer, soil stabilization, fly ash, volcanic ash, sodium silicate, sodium hydroxide, sodium aluminate, unconfined compressive strength, sulfuric acid resistance, structural fill, geopolymer microstructure
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