Dielectric properties of oriented PbZrO3 thin films grown by sol-gel process
Abstract
Antiferroelectric PbZrO3 (PZ) films have been fabricated on LaNiO3/Pt/Ti/SiO2/Si substrates using a sol-gel process. The films with perovskite structure showed highly 〈001〉 preferred orientation. An antiferroelectric phase was identified by the presence of 1/4{110} superlattice spots in a [001] selected area electron diffraction pattern. The field-induced antiferroelectric to ferroelectric phase switching was demonstrated at room temperature with full saturation and a maximum polarization of 40 μC/cm2. Dielectric properties were investigated as a function of both temperature and frequency. The presence of a conductive buffer layer of LaNiO3 on Pt/Ti/SiO2/Si substrate enabled the growth of high quality and highly oriented PZ antiferroelectric thin films that showed near zero remanent polarization and squared hysteresis loops.
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- Authors
- Zhai, J., Yao, Y., Li, X., Hung, T. F., Xu, Z. K., Chen, H., Colla, E. V., & Wu, T. B.
- Affiliations
- City University of Hong Kong (HK)
- University of Illinois Urbana-Champaign (US)
- National Tsing Hua University (TW)
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2002-10-01
- Volume
- 92
- Issue
- 7
- Pages
- 3990-3994
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W1604586397
- Semantic Scholar
- fe3487eadbdfcf45665ca998902db1c632ea902f
- Cited by
- 40
- References
- 18
- Citations by year
- 2023: 2 · 2022: 1 · 2021: 1 · 2020: 1 · 2019: 2 · 2018: 2 · 2017: 2 · 2016: 3 · 2015: 1 · 2014: 1 · 2013: 1
- FWCI
- 2.11
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Physics (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Ferroelectric and Negative Capacitance Devices
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Keywords
- PbZrO3, antiferroelectric thin films, dielectric properties, LaNiO3 buffer layer, remanent polarization, hysteresis loops, frequency and temperature dependence, perovskite structure
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