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Structural and magnetic properties of transition metal substituted ZnO
Open accessAbstract
Structural and magnetic properties have been studied for polycrystalline Zn1−xTMxO, where TM (transition metal ions)=Mn, Fe, and Co. No bulk ferromagnetism was observed for single-phase materials, contrary to the existing theories. Single-phase samples demonstrate paramagnetic Curie–Weiss behavior with antiferromagnetic interactions, similar to other diluted magnetic semiconductors. Nonoptimal synthesis conditions lead to formation of second phases that are responsible for spin-glass behavior {ZnMnO3 impurity for Zn1−xMnxO [S. Kolesnik et al., J. Supercond. 15, 251 (2002)]} or high-temperature ferromagnetic ordering [Co metal for Zn1−xCoxO with the Curie temperature TC>800 K or (Zn,Fe)3O4 for Zn1−xFexO with TC=440 K].
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Metadata
- Authors
- Kolesnik, S., Dabrowski, B., & Mais, J.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2004-03-01
- Volume
- 95
- Issue
- 5
- Pages
- 2582-2586
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W2027517119
- Cited by
- 274
- References
- 8
- FWCI
- 17.50
- Type
- journal article
- Language
- en
- Open access
- green
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