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Phase Equilibrium in the System Calcite-Aragonite
Abstract
The equilibrium curve for two of the phases of CaCO3, calcite-aragonite, has been determined as a function of temperature and pressure over the range 25–80°C and several thousand kg/cm2, using the electrical conductivity of aqueous solutions of each form. Aragonite is proved to be the high pressure modification. From the determined equilibrium curve, various thermodynamic quantities are obtained in a more accurate fashion than previously possible. All normal natural occurrences of aragonite must be due to metastable formation rather than equilibrium, since the geothermal gradient lies completely in the calcite field.
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Citations
Cited by
Plummer, L. N., & Busenberg, E. (1982) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(82)90056-4 · Cited by 1,886
Control of Aragonite or Calcite Polymorphism by Mollusk Shell Macromolecules
Falini, G., Albeck, S., Weiner, S., & Addadi, L. (1996) · Science · doi:10.1126/science.271.5245.67 · Cited by 1,437
Dolomitization by Seepage Refluxion
John Emery Adams (2), M. L. R. (1960) · AAPG Bulletin · doi:10.1306/0bda6263-16bd-11d7-8645000102c1865d · Cited by 425
Staudigel, P. T., & Swart, P. K. (2016) · Chemical Geology · doi:10.1016/j.chemgeo.2016.09.013 · Cited by 76
Radha, A. V., & Navrotsky, A. (2013) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2013.77.3 · Cited by 70
Metadata
- Authors
- Jamieson, J. C.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1953-08-01
- Volume
- 21
- Issue
- 8
- Pages
- 1385-1390
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2085997099
- Cited by
- 163
- References
- 0
- FWCI
- 2.58
- Type
- journal article
- Language
- en
- Open access
- closed
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