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Microscopic Observation of the Solidification of Small Metal Droplets
Abstract
The solidification behavior of small metal (10 to 100 micron diameter) droplets has been observed on a high temperature microscope stage. An abrupt change in surface appearance and in the case of high melting metals a sudden brightening (``blick'') accompanies solidification. The solidification temperatures observed for a collection of droplets may be widely distributed, but a significant, usually the major, fraction of the droplets supercool some maximum amount (ΔT-)max that is reproducible and characteristic of the metal. For many metals (ΔT-)max≈0.18 times the absolute melting temperature. (ΔT-)max is not much changed by wide variations in the cooling rate and droplet size. The growth rate of metal crystals is very great so that the solidification rate of the droplets is controlled by the nucleation frequency.
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Citations
Cited by
Confined crystallization of polymeric materials
Michell, R. M., & Müller, A. J. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2015.10.007 · Cited by 351
Nucleation and Crystallization in Diblock and Triblock Copolymers
Müller, A. J., Balsamo, V., & Arnal, M. L. (2005) · Advances in Polymer Science · doi:10.1007/12_001 · Cited by 294
Nucleation in undercooled liquids
Perepezko, J. H. (1984) · Materials Science and Engineering · doi:10.1016/0025-5416(84)90206-4 · Cited by 288
Self-Nucleation Effects on Polymer Crystallization
Sangroniz, L., Cavallo, D., & Müller, A. J. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00223 · Cited by 283
Homogeneous nucleation and fractionated crystallization in block copolymers
Müller, A. J., Balsamo, V., Arnal, M. L., Jakob, T., Schmalz, H., & Abetz, V. (2002) · Macromolecules · doi:10.1021/ma012026w · Cited by 226
Metadata
- Authors
- Turnbull, D., & Cech, R. E.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 1950-08-01
- Volume
- 21
- Issue
- 8
- Pages
- 804-810
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W2034216383
- Cited by
- 557
- References
- 0
- FWCI
- 7.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Turnbull, D., & Cech, R. E. (1950). Microscopic Observation of the Solidification of Small Metal Droplets. Journal of Applied Physics. https://doi.org/10.1063/1.1699763
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