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Cited by 349

The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.

Longitudinal Acoustical Vibrations of Finite Polymethylene Chains

Schaufele, R. F., Shimanouchi, T.·1967·The Journal of Chemical Physics

Abstract

The low-frequency Raman scattering spectra of finite polymethylene chains, observed utilizing laser excitation, show a band progression whose frequencies vary inversely and continuously as a function of chain length. It was established that these transitions arise from the longitudinal acoustical vibration of the chain skeleton and its overtones. These results are related to recent theoretical calculations for crystal vibrations of the infinite chain and are found to be in excellent quantitative agreement. An accurate spectroscopic value is derived for the elastic modulus of polyethylene.

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Cites

Show all 11 references

Research works printed but not linked: 13

  1. 1949, J. Chem. Phys., 17, 1102, 10.1063/1.1747121 · doi:10.1063/1.1747121
  2. 1962, J. Mol. Spectry., 9, 261, 10.1016/0022-2852(62)90236-9 · doi:10.1016/0022-2852(62)90236-9
  3. 1963, J. Mol. Spectrosc., 11, 422, 10.1016/0022-2852(63)90043-2 · doi:10.1016/0022-2852(63)90043-2
  4. 1963, Spectrochim. Acta, 19, 117, 10.1016/0371-1951(63)80096-X · doi:10.1016/0371-1951(63)80096-x
  5. 1965, J. Chem. Phys., 43, 2497, 10.1063/1.1697149 · doi:10.1063/1.1697149
  6. 1963, J. Chem. Phys., 38, 221, 10.1063/1.1733465 · doi:10.1063/1.1733465
  7. 1967, J. Polymer Sci. Pt. A, 2, 239
  8. 1953, J. Chem. Phys., 21, 2229
  9. 1966, J. Polymer Sci. Pt. C, 15, 75
  10. 1964, J. Polymer Sci. Pt. A, 2, 5075
  11. 1962, J. Polymer Sci., 59, 93, 10.1002/pol.1962.1205916708 · doi:10.1002/pol.1962.1205916708
  12. 1966, Nature, 212, 400, 10.1038/212400a0 · doi:10.1038/212400a0
  13. 1949, Trans. Faraday Soc., 45, 1131, 10.1039/tf9494501131 · doi:10.1039/tf9494501131

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Metadata

Authors
Schaufele, R. F., & Shimanouchi, T.
Venue
The Journal of Chemical Physics
Published
1967-11-01
Volume
47
Issue
9
Pages
3605-3610
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W1965280340
Cited by
349
References
11
FWCI
8.26
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Longitudinal Acoustical Vibrations of Finite Polymethylene Chains. https://app.cochat.ai/papers/10.1063/1.1712428
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Schaufele, R. F., & Shimanouchi, T. (1967). Longitudinal Acoustical Vibrations of Finite Polymethylene Chains. The Journal of Chemical Physics. https://doi.org/10.1063/1.1712428

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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