The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Theory of Molecular Size Distribution and Gel Formation in Branched-Chain Polymers
Abstract
The most probable distributions of molecular sizes are calculated for certain types of branched-chain polymers. The results represent an extension of the previous work of Flory, who showed that very large polymeric molecules appear suddenly at a critical extent of reaction, which is predicted to occur very nearly at the experimentally observed gel point. This transition from liquid to gel is shown to be analagous to the condensation of a saturated vapor. It is believed that the size distributions obtained herein will aid in a study of viscosity-molecular weight relationships in branched-chain polymers.
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Cites
Random Reorganization of Molecular Weight Distribution in Linear Condensation Polymers1
Flory, P. J. (1942) · Journal of the American Chemical Society · doi:10.1021/ja01261a049 · Cited by 135
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Metadata
- Authors
- Stockmayer, W. H.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1943-02-01
- Volume
- 11
- Issue
- 2
- Pages
- 45-55
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1987209504
- Cited by
- 1,895
- References
- 1
- FWCI
- 10.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Stockmayer, W. H. (1943). Theory of Molecular Size Distribution and Gel Formation in Branched-Chain Polymers. The Journal of Chemical Physics. https://doi.org/10.1063/1.1723803
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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