The DOI matches its Crossref record.
X-Ray Diffraction and Nuclear Quadrupole Resonance Studies of Chromium Trichloride
Abstract
The infinite-layer compound CrCl3 is found to undergo a first-order phase transformation near 240°K. The crystal structures of the high- and low-temperature phases have been elucidated by detailed x-ray diffraction and 35Cl nuclear quadrupole resonance studies. The previously reported structure for CrCl3 is shown to be incorrect. The present single-crystal diffraction results at 298° and 225°K give monoclinic (C2/m: a0=5.959 Å, b0=10.321, c0=6.114 Å, β=108.49°) and rhombohedral (R3̄: a0=5.942 Å, c0=17.333 Å) structures, respectively. The 35Cl quadrupole resonance frequencies, measured in polycrystalline samples, have been compared with results of field-gradient calculations based on the ionic point-charge model. The ionic contribution accounts for a large fraction of the total gradient making it impossible to evaluate the covalency parameters of the Cr–Cl bonds from the measured quadrupole coupling constants.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Zhang, W.-B., Qu, Q., Zhu, P., & Lam, C.-H. (2015) · Journal of Materials Chemistry C · doi:10.1039/c5tc02840j · Cited by 733
Monoclinic crystal structure ofα−RuCl3and the zigzag antiferromagnetic ground state
Johnson, R. D., Williams, S. C., Haghighirad, A. A., Singleton, J., Zapf, V., Manuel, P., Mazin, I. I., Li, Y., Jeschke, H. O., Valentí, R., et al. (2015) · Physical Review B · doi:10.1103/physrevb.92.235119 · Cited by 512
Emergent phenomena and proximity effects in two-dimensional magnets and heterostructures
Huang, B., McGuire, M. A., May, A. F., Xiao, D., Jarillo-Herrero, P., & Xu, X. (2020) · Nature Materials · doi:10.1038/s41563-020-0791-8 · Cited by 396
Magnetic behavior and spin-lattice coupling in cleavable van der Waals layered CrCl3 crystals
McGuire, M. A., Clark, G., KC, S., Chance, W. M., Jellison, G. E., Cooper, V. R., Xu, X., & Sales, B. C. (2017) · Physical Review Materials · doi:10.1103/physrevmaterials.1.014001 · Cited by 319
Successive magnetic phase transitions inα−RuCl3: XY-like frustrated magnet on the honeycomb lattice
Kubota, Y., Tanaka, H., Ono, T., Narumi, Y., & Kindo, K. (2015) · Physical Review B · doi:10.1103/physrevb.91.094422 · Cited by 317
Metadata
- Authors
- Morosin, B., & Narath, A.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1964-04-01
- Volume
- 40
- Issue
- 7
- Pages
- 1958-1967
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2046856822
- Cited by
- 212
- References
- 0
- FWCI
- 7.34
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: X-Ray Diffraction and Nuclear Quadrupole Resonance Studies of Chromium Trichloride. https://app.cochat.ai/papers/10.1063/1.1725428
- The paper
- Morosin, B., & Narath, A. (1964). X-Ray Diffraction and Nuclear Quadrupole Resonance Studies of Chromium Trichloride. The Journal of Chemical Physics. https://doi.org/10.1063/1.1725428
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
