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Dielectric Relaxation of Isoamyl Bromide
Abstract
The complex dielectric constant of isoamyl bromide has been measured at 1, 3, and 9 kMc between —75° and 25°C. Complex plane plots indicate an asymmetric, skewed-arc distribution of relaxation times, with the shape of the distribution function not being appreciably temperature dependent. A defect diffusion model is proposed to explain the dielectric behavior of this system. This model implies that the relaxation of a molecule is more probable immediately after one of its neighbors has relaxed than at an arbitrary time. A distribution of relaxation times is derived which, under the appropriate conditions, closely resembles that of the empirical skewed-arc function.
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Citations
Cites
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole, K. S., & Cole, R. H. (1941) · The Journal of Chemical Physics · doi:10.1063/1.1750906 · Cited by 10,152
Cited by
Enthalpy relaxation and recovery in amorphous materials
Hodge, I. M. (1994) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(94)90321-2 · Cited by 1,206
Glassy dynamics of kinetically constrained models
Ritort, F., & Sollich, P. (2003) · Advances in Physics · doi:10.1080/0001873031000093582 · Cited by 744
A new understanding of the dielectric relaxation of solids
Jonscher, A. K. (1981) · Journal of Materials Science · doi:10.1007/bf00542364 · Cited by 647
Heuer, A. (2008) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/20/37/373101 · Cited by 447
Coarse-grained microscopic model of glass formers
Garrahan, J. P., & Chandler, D. (2003) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1233719100 · Cited by 332
Metadata
- Authors
- Glarum, S. H.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1960-09-01
- Volume
- 33
- Issue
- 3
- Pages
- 639-643
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2048386513
- Cited by
- 389
- References
- 1
- FWCI
- 6.24
- Type
- journal article
- Language
- en
- Open access
- closed
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