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Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes
Abstract
The infrared spectra of twenty Co(III) carbonato complexes have been measured in a range between 4000 and 300 cm—1. Normal coordinate treatments were made with a model based on the unidentate and bidentate forms of the 1:1 (metal/ligand) complex. The theoretical band assignments and force constants obtained by these calculations confirm the validity of the previous qualitative conclusions based on the differences of symmetry and the frequency shifts of the unidentate and bidentate complexes. The Co(III)-O stretching bands were located at 440∼380 (antisymmetric) and at 400∼350 (symmetric) for the bidentate complexes, and at 360∼340 cm—1 for the unidentate complexes.
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Cited by
Busca, G., & Lorenzelli, V. (1982) · Materials Chemistry · doi:10.1016/0390-6035(82)90059-1 · Cited by 942
Infrared Study of the Adsorption of Methanol and Ethanol on Aluminum Oxide
Greenler, R. G. (1962) · The Journal of Chemical Physics · doi:10.1063/1.1733430 · Cited by 294
Infrared Study of Carbon Dioxide Adsorbed on Magnesium and Calcium Oxides
Fukuda, Y., & Tanabe, K. (1973) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.46.1616 · Cited by 140
Loring, J. S., Chen, J., Bénézeth, P., Qafoku, O., Ilton, E. S., Washton, N. M., Thompson, C. J., Martin, P. F., McGrail, B. P., Rosso, K. M., et al. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b01052 · Cited by 65
Metadata
- Authors
- Fujita, J., Martell, A. E., & Nakamoto, K.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1962-01-15
- Volume
- 36
- Issue
- 2
- Pages
- 339-345
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2049983763
- Cited by
- 175
- References
- 0
- FWCI
- 6.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Fujita, J., Martell, A. E., & Nakamoto, K. (1962). Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes. The Journal of Chemical Physics. https://doi.org/10.1063/1.1732506
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