The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Infrared Study of the Adsorption of Methanol and Ethanol on Aluminum Oxide
Abstract
The adsorbed surface species which result when aluminum oxide is exposed to methanol or ethanol vapor have been studied. Three different surface species have been identified for both methanol and ethanol. At 35°C a weakly bound layer of liquid alcohol is observed, which is removed by evacuation. Another species which persists after prolonged evacuation is identified as a surface methoxide in the case of methanol and an ethoxide in the case of ethanol. When the alumina sample is heated to 170°C in alcohol vapor a formate-like surface compound is formed from methanol and an acetate-like compound from ethanol. This interpretation of the surface structure has been checked by using deuterated methanols and C13-enriched methanol.
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Citations
Cites
Infrared and Raman Spectra of Polyatomic Molecules.
Herzberg, G., & Crawford, B. L. (1946) · The Journal of Physical Chemistry · doi:10.1021/j150447a021 · Cited by 3,323
THE VIBRATIONAL SPECTRA OF THE FORMATE, ACETATE, AND OXALATE IONS
Ito, K., & Bernstein, H. J. (1956) · Canadian Journal of Chemistry · doi:10.1139/v56-021 · Cited by 601
Surface Functionality of Amorphous Silica by Infrared Spectroscopy
McDonald, R. S. (1958) · The Journal of Physical Chemistry · doi:10.1021/j150568a004 · Cited by 439
Infrared Spectra of Methanol and Deuterated Methanols in Gas, Liquid, and Solid Phases
Falk, M., & Whalley, E. (1961) · The Journal of Chemical Physics · doi:10.1063/1.1701044 · Cited by 401
Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes
Fujita, J., Martell, A. E., & Nakamoto, K. (1962) · The Journal of Chemical Physics · doi:10.1063/1.1732506 · Cited by 175
Infrared studies of association in eleven alcohols
Smith, F. A., & Creitz, E. C. (1951) · Journal of research of the National Bureau of Standards · doi:10.6028/jres.046.021 · Cited by 136
Cited by
Specific Poisoning and Characterization of Catalytically Active Oxide Surfaces
Knöuzinger, H. (1976) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60315-6 · Cited by 426
Goldstein, D. N., McCormick, J. A., & George, S. M. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804296a · Cited by 330
Metadata
- Authors
- Greenler, R. G.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1962-11-01
- Volume
- 37
- Issue
- 9
- Pages
- 2094-2100
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2073035216
- Cited by
- 294
- References
- 6
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Greenler, R. G. (1962). Infrared Study of the Adsorption of Methanol and Ethanol on Aluminum Oxide. The Journal of Chemical Physics. https://doi.org/10.1063/1.1733430
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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