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Charge Exchange between Gaseous Ions and Atoms

Rapp, Donald, Francis, W. E.·1962·The Journal of Chemical Physics

Abstract

A calculation of symmetric resonant charge exchange cross sections has been made for a selection of atoms in the velocity range where the impact parameter method is applicable. Cross sections for other atoms can be estimated by interpolating in terms of their ionization potentials. The results are in fair agreement with experiment. A similar calculation has been attempted for asymmetric nonresonant charge exchange processes. The approximations used are more restrictive in this calculation, the calculations being only semiquantitative in nature. The cross section of an asymmetric charge exchange process is determined in terms of the ΔE of the reaction and the ``average'' ionization potential of the two atoms. The results are qualitatively in agreement with experiment. A very brief discussion of approaches for extrapolating data to lower velocities, where the rectilinear orbit impact parameter method is not applicable, is given.

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Metadata

Authors
Rapp, D., & Francis, W. E.
Venue
The Journal of Chemical Physics
Published
1962-12-01
Volume
37
Issue
11
Pages
2631-2645
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2000663474
Cited by
807
References
0
FWCI
9.47
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Charge Exchange between Gaseous Ions and Atoms. https://app.cochat.ai/papers/10.1063/1.1733066
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Rapp, D., & Francis, W. E. (1962). Charge Exchange between Gaseous Ions and Atoms. The Journal of Chemical Physics. https://doi.org/10.1063/1.1733066

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