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X-Ray Analysis of the Structure of Water
Abstract
X-ray diffraction patterns of water were obtained at five temperatures: 1.5°, 13°, 30°, 62°, and 83°C. The radiation was Cu Kα and Mo Kα, monochromated by reflection from a rocksalt crystal. Radial distribution curves for water at the five temperatures were obtained by a Fourier analysis of the x-ray intensity curves. The first peak is only partially resolved, and it is not possible to interpret the distribution curves uniquely in terms of a definite number of neighbors at definite distances. The results can be interpreted in terms of a structure in which the tendency of a water molecule to bond itself tetrahedrally to 4 neighboring molecules is only partially satisfied.
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Citations
Cited by
Raman Spectral Studies of Water Structure
Walrafen, G. E. (1964) · The Journal of Chemical Physics · doi:10.1063/1.1724992 · Cited by 629
Structural Analysis of Molecular Materials Using the Pair Distribution Function
Terban, M. W., & Billinge, S. J. L. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00237 · Cited by 426
Narten, A. H., & Levy, H. A. (1969) · Science · doi:10.1126/science.165.3892.447 · Cited by 314
A high-quality x-ray scattering experiment on liquid water at ambient conditions
Hura, G., Sorenson, J. M., Glaeser, R. M., & Head-Gordon, T. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1319614 · Cited by 306
Nuclear Magnetic Resonance Study of Collagen Hydration
Berendsen, H. J. C. (1962) · The Journal of Chemical Physics · doi:10.1063/1.1732460 · Cited by 278
Metadata
- Authors
- Morgan, J., & Warren, B. E.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1938-11-01
- Volume
- 6
- Issue
- 11
- Pages
- 666-673
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2033529067
- Cited by
- 305
- References
- 0
- FWCI
- 5.51
- Type
- journal article
- Language
- en
- Open access
- closed
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