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Charge transport and recombination in bulk heterojunction solar cells studied by the photoinduced charge extraction in linearly increasing voltage technique
Abstract
Charge carrier mobility and recombination in a bulk heterojunction solar cell based on the mixture of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C61 (PCBM) has been studied using the novel technique of photoinduced charge carrier extraction in a linearly increasing voltage (Photo-CELIV). In this technique, charge carriers are photogenerated by a short laser flash, and extracted under a reverse bias voltage ramp after an adjustable delay time (tdel). The Photo-CELIV mobility at room temperature is found to be μ=2×10−4cm2V−1s−1, which is almost independent on charge carrier density, but slightly dependent on tdel. Furthermore, determination of charge carrier lifetime and demonstration of an electric field dependent mobility is presented.
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Cited by
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
A polymer tandem solar cell with 10.6% power conversion efficiency
You, J., Dou, L., Yoshimura, K., Kato, T., Ohya, K., Moriarty, T., Emery, K., Chen, C.-C., Gao, J., Li, G., et al. (2013) · Nature Communications · doi:10.1038/ncomms2411 · Cited by 2,778
Molecular Semiconductors in Organic Photovoltaic Cells
Hains, A. W., Liang, Z., Woodhouse, M. A., & Gregg, B. A. (2010) · Chemical Reviews · doi:10.1021/cr9002984 · Cited by 935
High-performance multiple-donor bulk heterojunction solar cells
Yang, Y. (., Chen, W., Dou, L., Chang, W.-H., Duan, H.-S., Bob, B., Li, G., & Yang, Y. (2015) · Nature Photonics · doi:10.1038/nphoton.2015.9 · Cited by 527
Small is Powerful: Recent Progress in Solution‐Processed Small Molecule Solar Cells
Collins, S. D., Ran, N. A., Heiber, M. C., & Nguyen, T. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602242 · Cited by 414
Metadata
- Authors
- Mozer, A. J., Sariciftci, N. S., Lutsen, L., Vanderzande, D., Österbacka, R., Westerling, M., & Juška, G.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2005-03-08
- Volume
- 86
- Issue
- 11
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2090904611
- Cited by
- 214
- References
- 0
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mozer, A. J., Sariciftci, N. S., Lutsen, L., Vanderzande, D., Österbacka, R., Westerling, M., & Juška, G. (2005). Charge transport and recombination in bulk heterojunction solar cells studied by the photoinduced charge extraction in linearly increasing voltage technique. Applied Physics Letters. https://doi.org/10.1063/1.1882753
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