Laser ablation of a platinum target in water. III. Laser-induced reactions
Abstract
This is the third paper in our series studying the laser-target-liquid interactions occurring in laser ablation in liquids (LAL). Here, laser ablation of a platinum target in pure water at 355nm wavelength is studied as a function of laser energy. We describe three distinct reaction regimes between the ablated target species and water at different laser focusing conditions. At low laser fluence (<10J∕cm2), material removal is caused by laser heating of the platinum surface and the primary products are small clusters with a large percentage of platinum atoms in a nonzero oxidation state. At intermediate fluences (10–70J∕cm2), platinum nanoparticles are the primary products. Our previous studies demonstrated that in this fluence regime ablation occurs through both thermal vaporization and explosive ejection of molten droplets. In both cases reactivity is small due to the low reactivity of platinum with water. At high fluences (>70J∕cm2), we find large, faceted particles that are attributed to the drying of PtOx gels formed by reactive plasma etching of the target. Taken together these results demonstrate that significant tunability in the target-liquid interaction is possible during nanomaterial synthesis by LAL.
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Because ablation of the Pt target in these liquids was nonreactive, the nanoparticles obtained were in their elemental state.
“Because of the nonreactive nature of ablation of Pt target in these liquids, the nanoparticles obtained were in their elemental state [7].”
From Synthesis and Properties of Platinum Nanoparticles by Pulsed Laser Ablation in Liquid (2016) · cites this paper as [7]
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- Authors
- Nichols, W. T., Sasaki, T., & Koshizaki, N.
- Affiliations
- National Institute of Advanced Industrial Science and Technology (JP)
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2006-12-01
- Volume
- 100
- Issue
- 11
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W1993151419
- Cited by
- 105
- References
- 0
- Citations by year
- 2026: 3 · 2025: 4 · 2024: 6 · 2023: 6 · 2022: 7 · 2021: 8 · 2020: 4 · 2019: 5 · 2018: 3 · 2017: 11 · 2016: 5 · 2015: 7 · 2014: 3 · 2013: 4 · 2012: 8
- FWCI
- 1.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Physics (publishedVersion)
- Funders
- Japan Society for the Promotion of Science
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Engineering › Computational Mechanics › Laser Material Processing Techniques
- Physical Sciences › Engineering › Mechanics of Materials › Laser-induced spectroscopy and plasma
- Keywords
- laser ablation in liquid, platinum, water, laser-induced reactions, laser fluence, platinum nanoparticles, platinum clusters, oxidation state, thermal vaporization, molten droplets, plasma etching, nanomaterial synthesis
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