Synthesis of Magnetic Nanoparticles by Ultrashort Pulsed Laser Ablation of Iron in Different Liquids
Abstract
Magnetic nanoparticles were generated by ultrashort pulsed laser ablation of an iron target in water, methanol, ethanol, acetone and toluene. The relationship between ablation rate, liquid properties and the physical and chemical properties of the nanoparticles was studied. Composition, morphology and magnetic properties were investigated by TEM, XPS and vibrating-sample (VSM) and SQUID magnetometry. The properties of the generated nanoparticle ensembles reflected the influence of the liquid environment on the particle formation process. For example, the composition was strongly dependent on the carbon to oxygen ratio within the molecules of the liquid. In contrast to short pulsed laser ablation in liquids, the nanoparticles generated by ultrashort pulses had a higher level of polycrystallinity.
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NPs generated by ultrashort PLA possessed better polycrystallinity than the short PLA-produced NPs.
“The NPs generated by the ultrashort PLA possessed better polycrystallinity than the short PLA-produced NPs.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [107]
Kanitz et al. concluded that the molecular structure of the liquid medium dictates the nanostructural formation.
“Kanitz et al. [139] examined the structure and morphology of magnetic NPs using five solvents with femtosecond laser pulses and concluded that the molecular structure of the liquid medium dictates the nanostructural formation.”
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Surface morphology correlated with sputtering yield measurements of laser-ablated iron
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- Authors
- Kanitz, A., Hoppius, J. S., del Mar Sanz, M., Maicas, M., Ostendorf, A., & Gurevich, E. L.
- Affiliations
- Ruhr University Bochum (DE)
- Instituto de Sistemas Optoelectrónicos y Microstecnología (ISOM), E.T.S.I.T-U.P.M. Avda. Complutense 30 28004 Madrid Spain
- Corresponding author
- Kanitz, Alexander
- Gurevich, Evgeny L.
- Venue
- ChemPhysChem
- Publisher
- Wiley
- Published
- 2017-03-06
- Volume
- 18
- Issue
- 9
- Pages
- 1155-1164
- ISSN
- 1439-4235 (ISSN-L)
- 1439-7641
- OpenAlex
- W2586082588
- Cited by
- 67
- References
- 50
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 4 · 2023: 5 · 2022: 8 · 2021: 9 · 2020: 7 · 2019: 12 · 2018: 10 · 2017: 7
- FWCI
- 4.44
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemPhysChem (publishedVersion)
- PubMed (publishedVersion)
- Hispana (acceptedVersion)
- Archivo Digital UPM (Universidad Politécnica de Madrid) (acceptedVersion)
- Funders
- Deutsche Forschungsgemeinschaft (GU1075/3)
- Ministerio de Economía y Competitividad (MAT2014-52477-C5-1-P)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Engineering › Computational Mechanics › Laser Material Processing Techniques
- Physical Sciences › Materials Science › Materials Chemistry › Advanced Nanomaterials in Catalysis
- Keywords
- magnetic nanoparticles, iron nanoparticles, laser ablation in liquid, ablation rate, liquid properties, C/O ratio, nanoparticle composition, nanoparticle morphology, magnetic properties, polycrystallinity, methanol, ethanol, acetone, toluene, water
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