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Cited by 643

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Electric-field-induced phase changes in poly(vinylidene fluoride)

Davis, G. T., McKinney, J. E., Broadhurst, M. G., Roth, S. C.·1978·Journal of Applied Physics

Abstract

The antipolar crystal form of poly(vinylidene fluoride) can be made piezoelectric and pyroelecric by the temporary application of electric fields in excess of 1 MV/cm at room temperature. Infrared and x-ray diffraction data reveal that the polarization occurs in two stages. At fields near 1 MV/cm, a phase transition to a polar form II occurs with presumably no change in chain conformation. Fields near 5 MV/cm cause a change in conformation to produce form I. Our results indicate that at least a portion of the residual polarization occurs within the crystal phase of the polymer.

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Metadata

Authors
Davis, G. T., McKinney, J. E., Broadhurst, M. G., & Roth, S. C.
Venue
Journal of Applied Physics
Published
1978-10-01
Volume
49
Issue
10
Pages
4998-5002
ISSN
  • 0021-8979 (ISSN-L)
  • 1089-7550
OpenAlex
W2003994478
Cited by
643
References
0
FWCI
31.22
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Electric-field-induced phase changes in poly(vinylidene fluoride). https://app.cochat.ai/papers/10.1063/1.324446
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Davis, G. T., McKinney, J. E., Broadhurst, M. G., & Roth, S. C. (1978). Electric-field-induced phase changes in poly(vinylidene fluoride). Journal of Applied Physics. https://doi.org/10.1063/1.324446

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.