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Electric-field-induced phase changes in poly(vinylidene fluoride)
Abstract
The antipolar crystal form of poly(vinylidene fluoride) can be made piezoelectric and pyroelecric by the temporary application of electric fields in excess of 1 MV/cm at room temperature. Infrared and x-ray diffraction data reveal that the polarization occurs in two stages. At fields near 1 MV/cm, a phase transition to a polar form II occurs with presumably no change in chain conformation. Fields near 5 MV/cm cause a change in conformation to produce form I. Our results indicate that at least a portion of the residual polarization occurs within the crystal phase of the polymer.
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Citations
Cited by
Ferroelectric properties of vinylidene fluoride copolymers
Furukawa, T. (1989) · Phase Transitions · doi:10.1080/01411598908206863 · Cited by 1,161
Fang, J., Niu, H., Wang, H., Wang, X., & Lin, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee24230g · Cited by 257
Laroche, G., Marois, Y., Guidoin, R., King, M. W., Martin, L., How, T., & Douville, Y. (1995) · Journal of Biomedical Materials Research · doi:10.1002/jbm.820291209 · Cited by 202
Metadata
- Authors
- Davis, G. T., McKinney, J. E., Broadhurst, M. G., & Roth, S. C.
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 1978-10-01
- Volume
- 49
- Issue
- 10
- Pages
- 4998-5002
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W2003994478
- Cited by
- 643
- References
- 0
- FWCI
- 31.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electric-field-induced phase changes in poly(vinylidene fluoride). https://app.cochat.ai/papers/10.1063/1.324446
- The paper
- Davis, G. T., McKinney, J. E., Broadhurst, M. G., & Roth, S. C. (1978). Electric-field-induced phase changes in poly(vinylidene fluoride). Journal of Applied Physics. https://doi.org/10.1063/1.324446
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.