Cited by 25Photochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical StudiesLuminescence and Fluorescent Materials

Thermally controlled preferential molecular aggregation state in a thiacarbocyanine dye

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Passier, Rémy, Ritchie, James P., Toro, Carlos, Diaz, Carlos, Masunov, Artëm E., Belfield, Kevin D., Hernandez, Florencio E.·2010·The Journal of Chemical Physics

Abstract

Herein we report the experimental and theoretical study of the temperature dependence of a thiacarbocyanine dye in its monomer, H- and J-aggregates states. We demonstrate the ability to control the ratio of monomer, H- and/or J-aggregates with heat. We link such a control to the conformation dependence of the molecule. An alternative way to gain access to the dominating species without changing the concentration as a complete switching mechanism between all the present species is proposed. The results presented in this work lead to a better understanding of thiacarbocyanine dye’s behavior.

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Crossref · 10.1063/1.3483896

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44 of 44 references verified0 citation errors · 0 not checkable

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Authors
Passier, R., Ritchie, J. P., Toro, C., Diaz, C., Masunov, A. E., Belfield, K. D., & Hernandez, F. E.
Affiliations
  • University of Central Florida (US)
  • University of Central Florida 1 Department of Chemistry, , P.O. Box 162366, Orlando, Florida 32816-2366, USA
Venue
The Journal of Chemical Physics
Published
2010-10-07
Volume
133
Issue
13
Pages
134508-134508
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2004803502
Cited by
25
References
44
Citations by year
2026: 1 · 2025: 1 · 2024: 1 · 2022: 2 · 2020: 1 · 2017: 1 · 2016: 1 · 2015: 3 · 2014: 8 · 2013: 3 · 2012: 2
FWCI
1.27
Type
journal article
Language
en
Open access
Locations
  • The Journal of Chemical Physics (publishedVersion)
  • PubMed (publishedVersion)
  • Journal of International Crisis and Risk Communication Research (submittedVersion)
Funders
National Science Foundation
Topics
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
  • Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
Keywords
thiacarbocyanine dyes, H-aggregates, J-aggregates, temperature dependence, conformational dependence, thermal management, switching mechanism

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