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Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys
Abstract
Phase stability is an important topic for high entropy alloys (HEAs), but the understanding to it is very limited. The capability to predict phase stability from fundamental properties of constituent elements would benefit the alloy design greatly. The relationship between phase stability and physicochemical/thermodynamic properties of alloying components in HEAs was studied systematically. The mixing enthalpy is found to be the key factor controlling the formation of solid solutions or compounds. The stability of fcc and bcc solid solutions is well delineated by the valance electron concentration (VEC). The revealing of the effect of the VEC on the phase stability is vitally important for alloy design and for controlling the mechanical behavior of HEAs.
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“The intermediate VEC range of 6.87 -8 corresponds to mixed phases of FCC and BCC 37 -39 .”
From Recent advances in high-entropy superconductors (2024) · cites this paper as [37]
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Self-citation
Metadata
- Authors
- Guo, S., Ng, C., Lu, J., & Liu, C. T.
- Affiliations
- Hong Kong Polytechnic University (HK)
- City University of Hong Kong 2 College of Science and Engineering, , Kowloon, Hong Kong
- ORCID
- Venue
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Published
- 2011-05-15
- Volume
- 109
- Issue
- 10
- ISSN
- 0021-8979 (ISSN-L)
- 1089-7550
- OpenAlex
- W1991258650
- Cited by
- 2,911
- References
- 28
- Citations by year
- 2026: 347 · 2025: 423 · 2024: 406 · 2023: 346 · 2022: 335 · 2021: 254 · 2020: 182 · 2019: 173 · 2018: 138 · 2017: 83 · 2016: 76 · 2015: 67 · 2014: 39 · 2013: 31 · 2012: 10
- FWCI
- 45.92
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Physics (publishedVersion)
- PolyU Institutional Research Archive (Hong Kong Polytechnic University) (submittedVersion)
- Chalmers Research (Chalmers University of Technology) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › High Entropy Alloys Studies
- Physical Sciences › Engineering › Mechanical Engineering › Intermetallics and Advanced Alloy Properties
- Physical Sciences › Materials Science › Metals and Alloys › Metallic Glasses and Amorphous Alloys
- Keywords
- high-entropy alloys, phase stability, valence electron concentration, FCC solid solution, BCC solid solution, excess enthalpy, solid solution formation, alloy design, thermodynamic properties
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