The DOI matches its Crossref record.
NMR in rotating solids
Abstract
The NMR free induction decay from a spinning sample having inhomogeneous anisotropic interactions (chemical shifts, first order quadrupole couplings) takes the form of a train of rotational spin echoes. The Fourier transform of the echo envelope is a sharp spectrum from which the effects of anisotropy have been removed. The Fourier transform of the echo shape contains information concerning the anisotropies: This information can be extracted by a moment analysis. The effects of localized homonuclear spin–spin interactions are to convert the ’’isotropic’’ spectrum into a characteristic powder pattern. Second order quadrupole coupling produces a similar effect. It is shown in this case that the usual second-order level shifts cannot be used to calculated this pattern, which must be described by a proper average Hamiltonian theory. Finally it is shown that rotational spin echoes provide a convenient means of studying very slow random molecular rotations (τc≲1 sec).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
Lilly Thankamony, A. S., Wittmann, J. J., Kaushik, M., & Corzilius, B. (2017) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/j.pnmrs.2017.06.002 · Cited by 544
Magnetically-oriented phospholipid micelles as a tool for the study of membrane-associated molecules
Sanders, C. R., Hare, B. J., Howard, K. P., & Prestegard, J. H. (1994) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/0079-6565(94)80012-x · Cited by 420
Homonuclear radio frequency-driven recoupling in rotating solids
Bennett, A. E., Rienstra, C. M., Griffiths, J. M., Zhen, W., Lansbury, P. T., & Griffin, R. G. (1998) · The Journal of Chemical Physics · doi:10.1063/1.476420 · Cited by 353
Cheng, L. L., Ma, M. J., Becerra, L., Ptak, T., Tracey, I., Lackner, A., & González, R. G. (1997) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.94.12.6408 · Cited by 339
Study of structural evolution of silica gel using 1H and 29Si NMR
Vega, A. J., & Scherer, G. W. (1989) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(89)90276-7 · Cited by 128
Metadata
- Authors
- Maricq, M. M., & Waugh, J. S.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1979-04-01
- Volume
- 70
- Issue
- 7
- Pages
- 3300-3316
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1975487233
- Cited by
- 1,305
- References
- 0
- FWCI
- 13.30
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: NMR in rotating solids. https://app.cochat.ai/papers/10.1063/1.437915
- The paper
- Maricq, M. M., & Waugh, J. S. (1979). NMR in rotating solids. The Journal of Chemical Physics. https://doi.org/10.1063/1.437915
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
