The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Structuring in liquid alkanes between solid surfaces: Force measurements and mean-field theory
Abstract
Measurements have been made of the solvation forces between mica surfaces in the even-numbered n-alkanes from hexane to hexadecane. In all cases the force law is qualitatively very similar, characterized by a decaying oscillatory function of distance, as occurs for simple isotropic liquids. The spacing between successive minima in the force does not increase with carbon number, and is comparable to the width of a linear alkane molecule rather than its length or any average diameter. This suggests that the alkanes have some tendency towards a parallel orientation near the mica surfaces. The measurements give no indication of any strong repulsive component expected from mean-field theories of higher alkanes or polymers. The results of one such theory are presented, and the reasons for its failure to match the experimental data are discussed.
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Citations
Cites
Israelachvili, J. N., & Adams, G. E. (1978) · Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases · doi:10.1039/f19787400975 · Cited by 1,812
Self-citationPashley, R. M. (1981) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(81)90348-9 · Cited by 958
The drainage of thin liquid films between solid surfaces
Chan, D. Y. C., & Horn, R. G. (1985) · The Journal of Chemical Physics · doi:10.1063/1.449693 · Cited by 762
Self-citationMolecular layering of water in thin films between mica surfaces and its relation to hydration forces
Pashley, R. M., & Israelachvili, J. N. (1984) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(84)90063-8 · Cited by 417
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Cited by
Motions and Relaxations of Confined Liquids
Granick, S. (1991) · Science · doi:10.1126/science.253.5026.1374 · Cited by 992
Confinement effects on freezing and melting
Christenson, H. K. (2001) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/13/11/201 · Cited by 567
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Metadata
- Authors
- Christenson, H. K., Gruen, D. W. R., Horn, R. G., & Israelachvili, J. N.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1987-08-01
- Volume
- 87
- Issue
- 3
- Pages
- 1834-1841
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2091658534
- Cited by
- 330
- References
- 4
- FWCI
- 6.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Christenson, H. K., Gruen, D. W. R., Horn, R. G., & Israelachvili, J. N. (1987). Structuring in liquid alkanes between solid surfaces: Force measurements and mean-field theory. The Journal of Chemical Physics. https://doi.org/10.1063/1.453196
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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