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Cited by 278

The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.

Dielectric friction and the transition from adiabatic to nonadiabatic electron transfer. I. Solvation dynamics in Liouville space

Sparpaglione, Massimo, Mukamel, Shaul·1988·The Journal of Chemical Physics
DOI 10.1063/1.453922
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Abstract

A microscopic theory for electron transfer rates in a polar medium, which interpolates continuously from the adiabatic to the nonadiabatic limits, is developed. Both static (polarity) interactions, which affect the reaction energetics and dynamic (friction) effects, are incorporated using a macroscopic solvation coordinate, whose dynamics and statistical properties are related to the entire frequency and wave vector dependent dielectric function of the solvent ε(k,ω). The present approach is based on using an expansion of the density matrix in Liouville space and utilizing the analogy with the calculation of nonlinear optical line shapes. A new criterion for adiabaticity is derived, and the role of the solvent longitudinal dielectric relaxation in inducing the crossover from the nonadiabatic to the adiabatic regimes is clarified. The applicability of a Landau–Zener-type resumation for the rate is critically analyzed. The origin of the fractional power dependence of the rate on the solvent time scale, observed in several electron transfer and isomerization reactions, is discussed.

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Metadata

Authors
Sparpaglione, M., & Mukamel, S.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1988-03-01
Volume
88
Issue
5
Pages
3263-3280
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.453922
OpenAlex
W2086864852
Cited by
278
References
58
FWCI
13.98
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Dielectric friction and the transition from adiabatic to nonadiabatic electron transfer. I. Solvation dynamics in Liouville space. https://app.cochat.ai/papers/10.1063/1.453922
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Sparpaglione, M., & Mukamel, S. (1988). Dielectric friction and the transition from adiabatic to nonadiabatic electron transfer. I. Solvation dynamics in Liouville space. The Journal of Chemical Physics. https://doi.org/10.1063/1.453922

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.