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Cited by 222

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Ultrafast solvent dynamics: Connection between time resolved fluorescence and optical Kerr measurements

Cho, Minhaeng, Rosenthal, Sandra J., Scherer, Norbert F., Ziegler, Lawrence D., Fleming, Graham R.·1992·The Journal of Chemical Physics

Abstract

The vibrational characteristics of liquid dynamics are used to describe the ultrafast relaxations observed in time-dependent fluorescence Stokes shift [J. Chem. Phys. 95, 4715 (1991)] and heterodyne detected optical Kerr effect measurements on acetonitrile, via a Brownian oscillator model. Introducing a frequency distribution of vibrational modes makes it possible to compare the two experiments. The ultrafast decays observed in the fluorescence Stokes shift and optical Kerr signals are produced by destructive superposition of the high frequency, underdamped modes.

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Metadata

Authors
Cho, M., Rosenthal, S. J., Scherer, N. F., Ziegler, L. D., & Fleming, G. R.
Venue
The Journal of Chemical Physics
Published
1992-04-01
Volume
96
Issue
7
Pages
5033-5038
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2058604300
Cited by
222
References
1
FWCI
18.17
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultrafast solvent dynamics: Connection between time resolved fluorescence and optical Kerr measurements. https://app.cochat.ai/papers/10.1063/1.462746
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Cho, M., Rosenthal, S. J., Scherer, N. F., Ziegler, L. D., & Fleming, G. R. (1992). Ultrafast solvent dynamics: Connection between time resolved fluorescence and optical Kerr measurements. The Journal of Chemical Physics. https://doi.org/10.1063/1.462746

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